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However, due to the low\u2010lying \u03c3*\u2010orbitals of the tin\u2010substituent bond in stannoles, they are capable of \u03c3*\u2013\u03c0* conjugation in a way that is exclusive to heavier element containing heterocycles. This makes stannoles very interesting alternatives for purely organic heterocycles in material applications, in which optoelectronic properties are of interest. This Concept article will highlight the synthesis, reactivity and physical properties of stannoles and related fluorenostannoles. At first, a brief introduction to different types of tin\u2010containing heterocycles is presented, followed by a discussion on different approaches to prepare stannoles, their reactivity and their physical properties. 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