{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,23]],"date-time":"2025-10-23T16:53:56Z","timestamp":1761238436825,"version":"build-2065373602"},"reference-count":48,"publisher":"Wiley","issue":"62","license":[{"start":{"date-parts":[[2017,10,16]],"date-time":"2017-10-16T00:00:00Z","timestamp":1508112000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2017,11,7]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>When reacting the organic functionalized tin selenide clusters [(SnR<jats:sup>1<\/jats:sup>)<jats:sub>3<\/jats:sub>Se<jats:sub>4<\/jats:sub>Cl] (<jats:bold>A<\/jats:bold>, R<jats:sup>1<\/jats:sup>=CMe<jats:sub>2<\/jats:sub>CH<jats:sub>2<\/jats:sub>C(O)Me) or [(SnR<jats:sup>1<\/jats:sup>)<jats:sub>4<\/jats:sub>Se<jats:sub>6<\/jats:sub>] (<jats:bold>B<\/jats:bold>) with (SiMe<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>Se and [Ag(PPh<jats:sub>3<\/jats:sub>)<jats:sub>3<\/jats:sub>Cl] at \u221278\u2009\u00b0C in CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, a microcrystalline intermediate (compound <jats:bold>1<\/jats:bold>) precipitates, which was investigated by magic angle spinning (MAS) NMR spectroscopy, powder X\u2010ray diffraction (PXRD), energy dispersive X\u2010ray (EDX) spectroscopy, and quantum chemistry calculations, to derive information about its composition and structure. Compound <jats:bold>1<\/jats:bold> re\u2010dissolves under reorganization into the organo\u2010functionalized Ag\/Sn\/Se cluster compound [Ag<jats:sub>6<\/jats:sub>(\u03bc<jats:sub>6<\/jats:sub>\u2010Se)(Ag<jats:sub>8<\/jats:sub>Se<jats:sub>12<\/jats:sub>){(R<jats:sup>1<\/jats:sup>Sn)<jats:sub>2<\/jats:sub>Se<jats:sub>2<\/jats:sub>}<jats:sub>6<\/jats:sub>] (<jats:bold>2<\/jats:bold>), or the mixed\u2010valence cluster [(AgPPh<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>(Sn<jats:sup>II<\/jats:sup>Cl)<jats:sub>2<\/jats:sub>Se<jats:sub>2<\/jats:sub>{(R<jats:sup>1<\/jats:sup>Sn<jats:sup>IV<\/jats:sup>)<jats:sub>2<\/jats:sub>Se<jats:sub>2<\/jats:sub>}<jats:sub>2<\/jats:sub>] (<jats:bold>3<\/jats:bold>), depending on the presence or the exclusion of daylight, respectively. The addition of N<jats:sub>2<\/jats:sub>H<jats:sub>4<\/jats:sub>\u22c5H<jats:sub>2<\/jats:sub>O to a solution of <jats:bold>1<\/jats:bold> yields selectively [Ag<jats:sub>7<\/jats:sub>(\u03bc<jats:sub>7<\/jats:sub>\u2010Se)(Ag<jats:sub>7<\/jats:sub>Se<jats:sub>12<\/jats:sub>){(R<jats:sup>2<\/jats:sup>Sn)<jats:sub>2<\/jats:sub>Se<jats:sub>2<\/jats:sub>}<jats:sub>6<\/jats:sub>] (<jats:bold>4<\/jats:bold>, R<jats:sup>2<\/jats:sup>=CMe<jats:sub>2<\/jats:sub>CH<jats:sub>2<\/jats:sub>C(N<jats:sub>2<\/jats:sub>H<jats:sub>2<\/jats:sub>)Me), the Ag\/Sn\/Se core of which is isomeric to that of <jats:bold>2. 2<\/jats:bold>\u2013<jats:bold>4<\/jats:bold> were characterized by X\u2010ray diffraction. NMR spectroscopic studies on solutions of <jats:bold>1<\/jats:bold> indicate the co\u2010existence of different species.<\/jats:p>","DOI":"10.1002\/chem.201703614","type":"journal-article","created":{"date-parts":[[2017,9,18]],"date-time":"2017-09-18T11:06:40Z","timestamp":1505732800000},"page":"15607-15611","source":"Crossref","is-referenced-by-count":13,"title":["Formation and Structural Diversity of Organo\u2010Functionalized Tin\u2013Silver Selenide Clusters"],"prefix":"10.1002","volume":"23","author":[{"given":"Niklas","family":"Rinn","sequence":"first","affiliation":[{"name":"Fachbereich Chemie Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Strasse 4 35043 Marburg Germany"},{"name":"Wissenschaftliches Zentrum f\u00fcr Materialwissenschaften (WZMW) Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Strasse 35043 Marburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lukas","family":"Guggolz","sequence":"additional","affiliation":[{"name":"Fachbereich Chemie Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Strasse 4 35043 Marburg Germany"},{"name":"Wissenschaftliches Zentrum f\u00fcr Materialwissenschaften (WZMW) Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Strasse 35043 Marburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Katharina","family":"Gries","sequence":"additional","affiliation":[{"name":"Fachbereich Physik Philipps-Universit\u00e4t Marburg  Renthof 7 35032 Marburg Germany"},{"name":"Wissenschaftliches Zentrum f\u00fcr Materialwissenschaften (WZMW) Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Strasse 35043 Marburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kerstin","family":"Volz","sequence":"additional","affiliation":[{"name":"Fachbereich Physik Philipps-Universit\u00e4t Marburg  Renthof 7 35032 Marburg Germany"},{"name":"Wissenschaftliches Zentrum f\u00fcr Materialwissenschaften (WZMW) Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Strasse 35043 Marburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"J\u00fcrgen","family":"Senker","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Bayreuth  Universit\u00e4tsstrasse 30 95447 Bayreuth Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1325-9228","authenticated-orcid":false,"given":"Stefanie","family":"Dehnen","sequence":"additional","affiliation":[{"name":"Fachbereich Chemie Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Strasse 4 35043 Marburg Germany"},{"name":"Wissenschaftliches Zentrum f\u00fcr Materialwissenschaften (WZMW) Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Strasse 35043 Marburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2017,10,16]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19030360367"},{"key":"e_1_2_2_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)92632-9"},{"key":"e_1_2_2_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19871200712"},{"key":"e_1_2_2_4_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0567740872006041"},{"key":"e_1_2_2_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.594"},{"key":"e_1_2_2_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/om00031a054"},{"key":"e_1_2_2_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(94)05303-S"},{"key":"e_1_2_2_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja908917w"},{"key":"e_1_2_2_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200900523"},{"key":"e_1_2_2_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/om500014z"},{"key":"e_1_2_2_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc43649g"},{"key":"e_1_2_2_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic502627h"},{"key":"e_1_2_2_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201301521"},{"key":"e_1_2_2_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic100700f"},{"key":"e_1_2_2_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic900853e"},{"key":"e_1_2_2_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3749(200206)628:5<905::AID-ZAAC905>3.0.CO;2-S"},{"key":"e_1_2_2_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc00889c"},{"key":"e_1_2_2_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC05666C"},{"key":"e_1_2_2_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201503562"},{"key":"e_1_2_2_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/b508541a"},{"key":"e_1_2_2_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/b515623h"},{"key":"e_1_2_2_22_1","doi-asserted-by":"publisher","DOI":"10.1007\/BF01114537"},{"key":"e_1_2_2_23_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.1305880"},{"key":"e_1_2_2_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.20495"},{"key":"e_1_2_2_25_1","unstructured":"TURBOMOLE V6.1 2009 a Dev. 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