{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T04:15:26Z","timestamp":1760328926639,"version":"build-2065373602"},"reference-count":65,"publisher":"Wiley","issue":"59","license":[{"start":{"date-parts":[[2017,10,9]],"date-time":"2017-10-09T00:00:00Z","timestamp":1507507200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["SCHU 1170\/11-1"],"award-info":[{"award-number":["SCHU 1170\/11-1"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2017,10,20]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A dichloro\u2010cycloazatriphosphane that incorporates a cyclic NP<jats:sub>3<\/jats:sub> backbone could be synthesized using knowledge gained from the chemistry of N<jats:sub>2<\/jats:sub>P<jats:sub>2<\/jats:sub> and P<jats:sub>4<\/jats:sub> ring systems. It fills the gap between the congeneric compounds [ClP(\u03bc\u2010NR)]<jats:sub>2<\/jats:sub> and [ClP(\u03bc\u2010PR)]<jats:sub>2<\/jats:sub> (R=sterically demanding substituent), and thus contributes to the systematic development of nitrogen\u2013phosphorus chemistry in general. The title compound was studied with respect to its formation via a labile aminodiphosphene, which readily underwent different rearrangement reactions depending on the solvent. All compounds were fully characterized by experimental and computational methods.<\/jats:p>","DOI":"10.1002\/chem.201704278","type":"journal-article","created":{"date-parts":[[2017,9,12]],"date-time":"2017-09-12T12:05:27Z","timestamp":1505217927000},"page":"14738-14742","source":"Crossref","is-referenced-by-count":10,"title":["Dichloro\u2010Cycloazatriphosphane: The Missing Link between N<sub>2<\/sub>P<sub>2<\/sub> and P<sub>4<\/sub> Ring Systems in the Systematic Development of NP Chemistry"],"prefix":"10.1002","volume":"23","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9450-3407","authenticated-orcid":false,"given":"Jonas","family":"Bresien","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Chemie Universit\u00e4t Rostock  Albert-Einstein-Stra\u00dfe 3a 18059 Rostock Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7831-1410","authenticated-orcid":false,"given":"Alexander","family":"Hinz","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Oxford Chemistry Research Laboratory  12 Mansfield Road Oxford OX1 3TA UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9060-7065","authenticated-orcid":false,"given":"Axel","family":"Schulz","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie Universit\u00e4t Rostock  Albert-Einstein-Stra\u00dfe 3a 18059 Rostock Germany"},{"name":"Leibniz-Institut f\u00fcr Katalyse an der Universit\u00e4t Rostock e.V.  Albert-Einstein-Stra\u00dfe 29a 18059 Rostock Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tim","family":"Suhrbier","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie Universit\u00e4t Rostock  Albert-Einstein-Stra\u00dfe 3a 18059 Rostock Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Max","family":"Thomas","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie Universit\u00e4t Rostock  Albert-Einstein-Stra\u00dfe 3a 18059 Rostock Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0868-9987","authenticated-orcid":false,"given":"Alexander","family":"Villinger","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie Universit\u00e4t Rostock  Albert-Einstein-Stra\u00dfe 3a 18059 Rostock Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2017,10,9]]},"reference":[{"doi-asserted-by":"publisher","key":"e_1_2_2_1_1","DOI":"10.1016\/0010-8545(94)85018-6"},{"doi-asserted-by":"publisher","key":"e_1_2_2_2_1","DOI":"10.1016\/S0010-8545(00)00312-X"},{"doi-asserted-by":"publisher","key":"e_1_2_2_3_1","DOI":"10.1016\/S0010-8545(02)00033-4"},{"doi-asserted-by":"publisher","key":"e_1_2_2_4_1","DOI":"10.1039\/B514861H"},{"doi-asserted-by":"publisher","key":"e_1_2_2_5_1","DOI":"10.1021\/cr400547x"},{"doi-asserted-by":"publisher","key":"e_1_2_2_6_1","DOI":"10.1039\/C6DT01121G"},{"doi-asserted-by":"publisher","key":"e_1_2_2_7_1","DOI":"10.1002\/cber.187701001222"},{"doi-asserted-by":"publisher","key":"e_1_2_2_8_1","DOI":"10.1002\/cber.18940270197"},{"doi-asserted-by":"publisher","key":"e_1_2_2_9_1","DOI":"10.1002\/ange.19560682407"},{"doi-asserted-by":"publisher","key":"e_1_2_2_10_1","DOI":"10.1038\/2031167b0"},{"doi-asserted-by":"publisher","key":"e_1_2_2_11_1","DOI":"10.1039\/jr9650000057"},{"doi-asserted-by":"publisher","key":"e_1_2_2_12_1","DOI":"10.1039\/p19730000379"},{"doi-asserted-by":"publisher","key":"e_1_2_2_13_1","DOI":"10.1021\/ja00405a054"},{"doi-asserted-by":"publisher","key":"e_1_2_2_14_1","DOI":"10.1021\/ja00386a605"},{"doi-asserted-by":"publisher","key":"e_1_2_2_15_1","DOI":"10.1002\/anie.198817151"},{"doi-asserted-by":"publisher","key":"e_1_2_2_15_2","DOI":"10.1002\/ange.19881001220"},{"doi-asserted-by":"publisher","key":"e_1_2_2_16_1","DOI":"10.1021\/ic025759l"},{"doi-asserted-by":"publisher","key":"e_1_2_2_17_1","DOI":"10.1021\/ja027946o"},{"doi-asserted-by":"publisher","key":"e_1_2_2_18_1","DOI":"10.1021\/ic050770h"},{"doi-asserted-by":"publisher","key":"e_1_2_2_19_1","DOI":"10.1007\/s11224-010-9653-3"},{"doi-asserted-by":"publisher","key":"e_1_2_2_20_1","DOI":"10.1080\/13583149612331338697"},{"doi-asserted-by":"publisher","key":"e_1_2_2_21_1","DOI":"10.1039\/c0dt00700e"},{"key":"e_1_2_2_22_1","first-page":"2157","volume":"56","author":"Markovskii L. N.","year":"1986","journal-title":"Zh. Obshch. Khim."},{"doi-asserted-by":"publisher","key":"e_1_2_2_23_1","DOI":"10.1002\/chem.201403631"},{"doi-asserted-by":"publisher","key":"e_1_2_2_24_1","DOI":"10.1002\/anie.201500892"},{"doi-asserted-by":"publisher","key":"e_1_2_2_24_2","DOI":"10.1002\/ange.201500892"},{"doi-asserted-by":"publisher","key":"e_1_2_2_25_1","DOI":"10.1002\/chem.201503808"},{"doi-asserted-by":"publisher","key":"e_1_2_2_26_1","DOI":"10.1039\/C5DT03928B"},{"doi-asserted-by":"publisher","key":"e_1_2_2_27_1","DOI":"10.1039\/C5DT02757H"},{"doi-asserted-by":"publisher","key":"e_1_2_2_28_1","DOI":"10.1021\/acs.inorgchem.6b00218"},{"doi-asserted-by":"publisher","key":"e_1_2_2_29_1","DOI":"10.1021\/cr9003709"},{"doi-asserted-by":"publisher","key":"e_1_2_2_30_1","DOI":"10.1021\/cr100010e"},{"doi-asserted-by":"publisher","key":"e_1_2_2_31_1","DOI":"10.1016\/j.ccr.2010.12.016"},{"doi-asserted-by":"publisher","key":"e_1_2_2_32_1","DOI":"10.1002\/anie.198305521"},{"doi-asserted-by":"publisher","key":"e_1_2_2_32_2","DOI":"10.1002\/ange.19830950723"},{"doi-asserted-by":"publisher","key":"e_1_2_2_33_1","DOI":"10.1002\/mrc.1260330110"},{"doi-asserted-by":"publisher","key":"e_1_2_2_34_1","DOI":"10.1002\/anie.198712561"},{"doi-asserted-by":"publisher","key":"e_1_2_2_34_2","DOI":"10.1002\/ange.19870991220"},{"doi-asserted-by":"publisher","key":"e_1_2_2_35_1","DOI":"10.1002\/anie.201003031"},{"doi-asserted-by":"publisher","key":"e_1_2_2_35_2","DOI":"10.1002\/ange.201003031"},{"doi-asserted-by":"publisher","key":"e_1_2_2_36_1","DOI":"10.1002\/zaac.201100448"},{"doi-asserted-by":"publisher","key":"e_1_2_2_37_1","DOI":"10.1039\/b914370j"},{"doi-asserted-by":"publisher","key":"e_1_2_2_38_1","DOI":"10.1002\/chem.201403964"},{"doi-asserted-by":"publisher","key":"e_1_2_2_39_1","DOI":"10.1002\/ejic.201600321"},{"doi-asserted-by":"publisher","key":"e_1_2_2_40_1","DOI":"10.1016\/0277-5387(95)00414-9"},{"doi-asserted-by":"publisher","key":"e_1_2_2_41_1","DOI":"10.1080\/10426509708545624"},{"doi-asserted-by":"publisher","key":"e_1_2_2_42_1","DOI":"10.1002\/zaac.200400234"},{"doi-asserted-by":"publisher","key":"e_1_2_2_43_1","DOI":"10.1002\/zaac.200500016"},{"doi-asserted-by":"publisher","key":"e_1_2_2_44_1","DOI":"10.1021\/om00047a006"},{"doi-asserted-by":"publisher","key":"e_1_2_2_45_1","DOI":"10.1139\/v02-161"},{"doi-asserted-by":"publisher","key":"e_1_2_2_46_1","DOI":"10.1002\/zaac.19855280902"},{"doi-asserted-by":"publisher","key":"e_1_2_2_47_1","DOI":"10.1021\/ja00385a060"},{"doi-asserted-by":"publisher","key":"e_1_2_2_48_1","DOI":"10.1002\/anie.198301551"},{"key":"e_1_2_2_48_2","first-page":"154","volume":"95","year":"1983","journal-title":"Angew. Chem."},{"doi-asserted-by":"publisher","key":"e_1_2_2_49_1","DOI":"10.1002\/anie.198609191"},{"doi-asserted-by":"publisher","key":"e_1_2_2_49_2","DOI":"10.1002\/ange.19860981006"},{"doi-asserted-by":"publisher","key":"e_1_2_2_50_1","DOI":"10.1021\/ic50005a008"},{"doi-asserted-by":"publisher","key":"e_1_2_2_51_1","DOI":"10.1002\/zaac.19814811020"},{"doi-asserted-by":"publisher","key":"e_1_2_2_52_1","DOI":"10.1002\/zaac.19865380709"},{"unstructured":"E.\u2005D. Glendening J.\u2005K. Badenhoop A.\u2005E. Reed J.\u2005E. Carpenter J.\u2005A. Bohmann C.\u2005M. Morales C.\u2005R. Landis F. Weinhold NBO 6.0 Theoretical Chemistry Institute University of Wisconsin Madison MI (USA) 2013.","key":"e_1_2_2_53_1"},{"doi-asserted-by":"publisher","key":"e_1_2_2_54_1","DOI":"10.1021\/jacs.5b00959"},{"doi-asserted-by":"publisher","key":"e_1_2_2_55_1","DOI":"10.1039\/C5DT02711J"},{"doi-asserted-by":"publisher","key":"e_1_2_2_56_1","DOI":"10.1002\/chem.201601916"},{"doi-asserted-by":"publisher","key":"e_1_2_2_57_1","DOI":"10.1002\/chem.200901472"},{"unstructured":"Detailed information on computational studies can be found in the Supporting Information.","key":"e_1_2_2_58_1"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.201704278","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201704278","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T03:28:41Z","timestamp":1760326121000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.201704278"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2017,10,9]]},"references-count":65,"journal-issue":{"issue":"59","published-print":{"date-parts":[[2017,10,20]]}},"alternative-id":["10.1002\/chem.201704278"],"URL":"https:\/\/doi.org\/10.1002\/chem.201704278","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"type":"print","value":"0947-6539"},{"type":"electronic","value":"1521-3765"}],"subject":[],"published":{"date-parts":[[2017,10,9]]}}}