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Unlike its type\u2005III structural analogue <jats:bold>[2(H<jats:sub>2<\/jats:sub>O)(OTf)]<jats:sup>+<\/jats:sup><\/jats:bold> active toward N<jats:sub>2<\/jats:sub>O reduction, this new type\u2005I compound is inactive. This outcome opens new perspectives for a rational for N<jats:sub>2<\/jats:sub>O activation using bio\u2010inspired Cu\/S complexes, especially on the role of the valence localization\/delocalization and the Cu\u2212Cu bond on the reactivity.<\/jats:p>","DOI":"10.1002\/chem.201704737","type":"journal-article","created":{"date-parts":[[2017,11,29]],"date-time":"2017-11-29T12:11:39Z","timestamp":1511957499000},"page":"5060-5063","source":"Crossref","is-referenced-by-count":6,"title":["Valence Localization at a Bio\u2010inspired Mixed\u2010Valent {Cu<sub>2<\/sub>S}<sup>2+<\/sup> Motif upon Solvation in Acetonitrile: Effect on Nitrous Oxide Reductase (N<sub>2<\/sub>Or) Activity"],"prefix":"10.1002","volume":"24","author":[{"given":"Charl\u00e8ne","family":"Esmieu","sequence":"first","affiliation":[{"name":"Univ. 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