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Electron\u2010withdrawing C<jats:sub>2<\/jats:sub>F<jats:sub>5<\/jats:sub> groups significantly influence the polarity of the tin\u2013hydrogen bond, which allows facile deprotonation of the compound, even in water. The utility of this electron\u2010deficient stannane was illustrated in hydrostannylations of alkenes and alkynes, as well as in dehalogenation reactions. The remarkably high reactivity of HSn(C<jats:sub>2<\/jats:sub>F<jats:sub>5<\/jats:sub>)<jats:sub>3<\/jats:sub> is demonstrated in fast hydrostannylations, even in the absence of activators, whereby the regioselectivity of this process turns out to be solvent dependent. It is of great advantage that in dehalogenation reactions volatile halogenotris(pentafluoroethyl)stannanes, XSn(C<jats:sub>2<\/jats:sub>F<jats:sub>5<\/jats:sub>)<jats:sub>3<\/jats:sub> (X=I, Br), are formed that allow facile separation of the tin\u2010containing byproducts from the reaction mixtures.<\/jats:p>","DOI":"10.1002\/chem.201705068","type":"journal-article","created":{"date-parts":[[2017,12,6]],"date-time":"2017-12-06T11:38:44Z","timestamp":1512560324000},"page":"2699-2708","source":"Crossref","is-referenced-by-count":12,"title":["Tris(pentafluoroethyl)stannane: Tin Hydride Chemistry with an Electron\u2010Deficient Stannane"],"prefix":"10.1002","volume":"24","author":[{"given":"Markus","family":"Wiesemann","sequence":"first","affiliation":[{"name":"Centrum f\u00fcr Molekulare Materialien Fakult\u00e4t f\u00fcr Chemie Universit\u00e4t Bielefeld  Universit\u00e4tsstra\u00dfe 25 33615 Bielefeld Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mark","family":"Niemann","sequence":"additional","affiliation":[{"name":"Centrum f\u00fcr Molekulare Materialien Fakult\u00e4t f\u00fcr Chemie Universit\u00e4t Bielefeld  Universit\u00e4tsstra\u00dfe 25 33615 Bielefeld Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Johannes","family":"Kl\u00f6sener","sequence":"additional","affiliation":[{"name":"Centrum f\u00fcr Molekulare Materialien Fakult\u00e4t f\u00fcr Chemie Universit\u00e4t Bielefeld  Universit\u00e4tsstra\u00dfe 25 33615 Bielefeld Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Beate","family":"Neumann","sequence":"additional","affiliation":[{"name":"Centrum f\u00fcr Molekulare Materialien Fakult\u00e4t f\u00fcr Chemie Universit\u00e4t Bielefeld  Universit\u00e4tsstra\u00dfe 25 33615 Bielefeld Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hans\u2010Georg","family":"Stammler","sequence":"additional","affiliation":[{"name":"Centrum f\u00fcr Molekulare Materialien Fakult\u00e4t f\u00fcr Chemie Universit\u00e4t Bielefeld  Universit\u00e4tsstra\u00dfe 25 33615 Bielefeld Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9610-8478","authenticated-orcid":false,"given":"Berthold","family":"Hoge","sequence":"additional","affiliation":[{"name":"Centrum f\u00fcr Molekulare Materialien Fakult\u00e4t f\u00fcr Chemie Universit\u00e4t Bielefeld  Universit\u00e4tsstra\u00dfe 25 33615 Bielefeld Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2018,1,30]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"crossref","first-page":"131","DOI":"10.1191\/0748233705th220oa","volume":"21","author":"Hoth A.","year":"2005","journal-title":"Toxicol. 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