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Single crystal structures are presented of four compounds, (C<jats:sub>4<\/jats:sub>C<jats:sub>1<\/jats:sub>C<jats:sub>1<\/jats:sub>Im)<jats:sub>5<\/jats:sub>[Sn<jats:sub>9<\/jats:sub>Se<jats:sub>20<\/jats:sub>][BF<jats:sub>4<\/jats:sub>] (<jats:bold>1<\/jats:bold>, Im=imidazolium), (DMMPH)<jats:sub>4<\/jats:sub>[Sn<jats:sub>2<\/jats:sub>Se<jats:sub>6<\/jats:sub>] (<jats:bold>2<\/jats:bold>, DMMP=2,6\u2010dimethylmorpholine), (C<jats:sub>2<\/jats:sub>C<jats:sub>1<\/jats:sub>Im)<jats:sub>2<\/jats:sub>(DMMPH)<jats:sub>2<\/jats:sub>[Sn<jats:sub>6<\/jats:sub>Se<jats:sub>14<\/jats:sub>] (<jats:bold>3<\/jats:bold>), and K<jats:sub>2<\/jats:sub>[Sn<jats:sub>3<\/jats:sub>Se<jats:sub>7<\/jats:sub>] (<jats:bold>4<\/jats:bold>), and how the chosen ionic liquid anion, and the reaction temperature, influences the product spectrum is discussed: Notably, <jats:bold>1<\/jats:bold> contains an entire formula unit of the ionic liquid, (C<jats:sub>4<\/jats:sub>C<jats:sub>1<\/jats:sub>C<jats:sub>1<\/jats:sub>Im)[BF<jats:sub>4<\/jats:sub>], while <jats:bold>4<\/jats:bold> contains neither the cation nor the anion of the ionic liquid\u2014both observations being very uncommon for ionothermal syntheses. Three further compounds were obtained that exhibit strong disorder in the crystal structures (<jats:bold>I<\/jats:bold>\u2010<jats:bold>III<\/jats:bold>), for which only their anionic substructures are discussed herein. Compound <jats:bold>4<\/jats:bold> and <jats:bold>I\u2010III<\/jats:bold> are based on the same layered selenidostannate substructure, 2D\u2010{[Sn<jats:sub>3<\/jats:sub>Se<jats:sub>7<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup>}, yet with different inter\u2010layer distances, which is clearly reflected in the crystal colors and quantitative optical absorption properties.<\/jats:p>","DOI":"10.1002\/chem.201705297","type":"journal-article","created":{"date-parts":[[2017,12,20]],"date-time":"2017-12-20T12:42:45Z","timestamp":1513773765000},"page":"3474-3480","source":"Crossref","is-referenced-by-count":14,"title":["The Role of [BF<sub>4<\/sub>]<sup>\u2212<\/sup> and [B(CN)<sub>4<\/sub>]<sup>\u2212<\/sup> Anions in the Ionothermal Synthesis of Chalcogenidometalates"],"prefix":"10.1002","volume":"24","author":[{"given":"Silke","family":"Santner","sequence":"first","affiliation":[{"name":"Fachbereich Chemie and Wissenschaftliches Zentrum f\u00fcr, Materialwissenschaften Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Strasse 4 35032 Marburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jan A. 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