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Although <jats:bold>6\u2009c<\/jats:bold> proves to be too unstable, the S,S\u2010dianion <jats:bold>6\u2009a<\/jats:bold> and ambidentate S,Se\u2010dianion <jats:bold>6\u2009b<\/jats:bold> are readily transferred intact to main group and transition metal elements, producing a range of new cage and coordination compounds. While their coordination characteristics are in many ways similar to closely\u2010related isoelectronic phosph(V)azane anions [(E)(RN=)P(\u03bc\u2010N<jats:italic>t<\/jats:italic>Bu)]<jats:sub>2<\/jats:sub><jats:sup>2\u2212<\/jats:sup>, the sterically unhindered nature of <jats:bold>6<\/jats:bold> introduces an expanded range of coordination modes, that is, facial S,S\u2010 and Se,Se\u2010bonding as well as side\u2010on S,Se\u2010coordination. All of these bonding modes are observed for the amibidentate S,Se dianion <jats:bold>6\u2009b<\/jats:bold>.<\/jats:p>","DOI":"10.1002\/chem.201705413","type":"journal-article","created":{"date-parts":[[2017,12,7]],"date-time":"2017-12-07T03:06:45Z","timestamp":1512616005000},"page":"2013-2019","source":"Crossref","is-referenced-by-count":5,"title":["Flexible Bonding of the Phosph(V)azane Dianions [S(E)P(\u03bc\u2010N<i>t<\/i>Bu)]<sub>2<\/sub><sup>2\u2212<\/sup>"],"prefix":"10.1002","volume":"24","author":[{"given":"Alex J.","family":"Plajer","sequence":"first","affiliation":[{"name":"Chemistry Department Cambridge University  Lensfield Road Cambridge CB2 1EW United Kingdom"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Raul","family":"Garcia\u2010Rodriguez","sequence":"additional","affiliation":[{"name":"GIR MIOMeT-IU Cinquima-Qu\u00edmica Inorg\u00e1nica Facultad de Ciencias Universidad de Valladolid  Campus Miguel, Delibes 47011 Valladolid Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Felix J.","family":"Rizzuto","sequence":"additional","affiliation":[{"name":"Chemistry Department Cambridge University  Lensfield Road Cambridge CB2 1EW United Kingdom"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9952-3877","authenticated-orcid":false,"given":"Dominic S.","family":"Wright","sequence":"additional","affiliation":[{"name":"Chemistry Department Cambridge University  Lensfield Road Cambridge CB2 1EW United Kingdom"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2018,1,4]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201302327"},{"key":"e_1_2_6_2_1","unstructured":"\u00a0"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200300487"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200400296"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2005.12.008"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/om050725h"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/om060753f"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1039\/b211009a"},{"key":"e_1_2_6_8_3","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2009.08.020"},{"key":"e_1_2_6_9_1","unstructured":"\u00a0"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(00)00312-X"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/b926428k"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/B514861H"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6DT01121G"},{"key":"e_1_2_6_14_1","unstructured":"\u00a0"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5DT02069G"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC04805F"},{"key":"e_1_2_6_17_1","unstructured":"\u00a0"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20020916)41:18<3468::AID-ANIE3468>3.0.CO;2-W"},{"key":"e_1_2_6_18_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20020916)114:18<3618::AID-ANGE3618>3.0.CO;2-Q"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic001093o"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.197704861"},{"key":"e_1_2_6_20_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19770890733"},{"key":"e_1_2_6_21_1","unstructured":"For example"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic001173s"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1039\/C2DT32716C"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201303884"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.5b00161"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5DT00159E"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4DT03257H"},{"key":"e_1_2_6_28_1","unstructured":"Search of the Cambridge Crystallographic Data Base October 2017."},{"key":"e_1_2_6_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc32809g"},{"key":"e_1_2_6_30_1","first-page":"290","volume-title":"Inorganic Chemistry: Principles of Structure and Reactivity, 4th\u2005ed.","author":"Huyeey J. 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