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Using transition\u2010metal\u2010substituted lacunary polyoxotungstates in place of the lanthanide reactant, new phosphonate\u2010functionalized silver(I)\u2013copper(II) ethynide clusters [Ag<jats:sub>34<\/jats:sub>Cu<jats:sub>6<\/jats:sub> (<jats:bold>3<\/jats:bold>) and Ag<jats:sub>37<\/jats:sub>Cu<jats:sub>6<\/jats:sub> (<jats:bold>4<\/jats:bold>)] and silver(I) ethynide clusters [Ag<jats:sub>51<\/jats:sub> (<jats:bold>5<\/jats:bold>) and Ag<jats:sub>72<\/jats:sub> (<jats:bold>6<\/jats:bold>)] were obtained. The structures of complexes <jats:bold>3<\/jats:bold>\u2013<jats:bold>6<\/jats:bold> feature core\u2013shell arrangements, in which silver(I)\u2013copper(II) or silver(I) ethynide cluster shells stabilized by peripheral phosphonate ligands enclose different kinds of tungstate core templates.<\/jats:p>","DOI":"10.1002\/chem.201705906","type":"journal-article","created":{"date-parts":[[2018,2,23]],"date-time":"2018-02-23T01:26:38Z","timestamp":1519349198000},"page":"6762-6768","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":29,"title":["High\u2010Nuclearity Heterometallic <i>tert<\/i>\u2010Butylethynide Clusters Assembled with <i>tert<\/i>\u2010Butylphosphonate"],"prefix":"10.1002","volume":"24","author":[{"given":"Guang\u2010Xiong","family":"Duan","sequence":"first","affiliation":[{"name":"State Key Laboratory of Materials Processing and Die &amp; Mould Technology School of Materials Science and Engineering Huazhong University of Science and Technology (HUST)  Wuhan 430074 P.R. 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