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All twelve \u03bc<jats:sup>2<\/jats:sup>\u2010oxo groups on the edges of the Lindqvist\u2010type {V<jats:sub>6<\/jats:sub>O<jats:sub>19<\/jats:sub>} core were replaced by alkoxo ligands. The absence of a negative charge and the closed organic shell make these neutral mixed\u2010valence compounds very stable towards hydrolysis and well soluble in almost all common organic solvents. These are important advantages over classical POMs. By post\u2010functionalization through copper(I)\u2010catalyzed Huisgen cycloaddition or imine formation, various organic moieties could be introduced. Even a well\u2010soluble trimer composed of three hexanuclear vanadium units connected through an aromatic triimino core was synthesized and studied. The diverse redox behavior, the versatile reactivity, the good stability, and the excellent solubility make our vanadium compounds highly interesting for applications as building blocks in macromolecular chemistry as well as redox labels in biochemistry.<\/jats:p>","DOI":"10.1002\/chem.201800041","type":"journal-article","created":{"date-parts":[[2018,1,9]],"date-time":"2018-01-09T15:40:33Z","timestamp":1515512433000},"page":"2785-2789","source":"Crossref","is-referenced-by-count":21,"title":["Versatile Organic Chemistry on Vanadium\u2010Based Multi\u2010Electron Reservoirs"],"prefix":"10.1002","volume":"24","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7247-8781","authenticated-orcid":false,"given":"Olaf","family":"Nachtigall","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Chemie und Biochemie Freie Universit\u00e4t Berlin  Fabeckstra\u00dfe\u200534\u201336 14195 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5079-7308","authenticated-orcid":false,"given":"Johann","family":"Spandl","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie und Biochemie Freie Universit\u00e4t Berlin  Fabeckstra\u00dfe\u200534\u201336 14195 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2018,2,6]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/B0-08-043748-6\/03035-8"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/B0-08-043748-6\/03036-X"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr500390v"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cs35119f"},{"key":"e_1_2_7_5_1","first-page":"287","volume-title":"Advances in Inorganic Chemistry, Vol.\u200569","author":"Errington R. 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