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The method allows a straightforward access to the desired heterocyclic scaffold bearing an all\u2010carbon \u03b1\u2010quaternary stereogenic center in high yields and good to excellent enantioselectivities. To further demonstrate the synthetic utility of the method, the allylated products were further converted to various versatile chiral building blocks, including a chiral pyrrolidine and a spirocyclic derivative, using selective transformations.<\/jats:p>","DOI":"10.1002\/chem.201800920","type":"journal-article","created":{"date-parts":[[2018,4,10]],"date-time":"2018-04-10T21:09:56Z","timestamp":1523394596000},"page":"8076-8080","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":24,"title":["Highly Enantioselective, Base\u2010Free Synthesis of \u03b1\u2010Quaternary Succinimides through Catalytic Asymmetric Allylic Alkylation"],"prefix":"10.1002","volume":"24","author":[{"given":"Tao","family":"Song","sequence":"first","affiliation":[{"name":"Laboratoire de Chimie Organique, Institute of Chemistry Biology and Innovation (CBI)\u2013ESPCI Paris\/CNRS, (UMR8231)\/PSL* Research University  10 rue Vauquelin 75231 Paris Cedex 05 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