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Moreover, and due to the low stability of thiol\u2013gold chemistry, contributions to the functionalisation of gold substrates with linkers that provide a more stable platform for the immobilisation of electroactive or biological molecules are highly appreciated. Herein, it is demonstrated that a carboxylated organotin compound can be successfully grafted onto gold substrates to form a highly stable organic layer with reactivity for subsequent binding to an aminated molecule. A battery of techniques were used to characterise the surface chemistry. The grafted layer was used to anchor aminoferrocene and subjected to both thermostability tests and long\u2010term stability studies over a period of one year, demonstrating thermostability up to 90\u2009\u00b0C and storage stability for at least 12\u2005months at 4\u2009\u00b0C protected from light. The stable surface tethering of molecules on gold substrates can be exploited in a plethora of applications, including molecular techniques, such as solid\u2010phase amplification and solid\u2010phase melting curve analysis, that require elevated temperature stability, as well as biosensors, which require long\u2010term storage stability.<\/jats:p>","DOI":"10.1002\/chem.201801854","type":"journal-article","created":{"date-parts":[[2018,5,21]],"date-time":"2018-05-21T14:40:41Z","timestamp":1526913641000},"page":"11177-11184","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Stable Carboxylate\u2010Terminated Gold Surfaces Produced by Spontaneous Grafting of an Alkyltin Compound"],"prefix":"10.1002","volume":"24","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9423-0055","authenticated-orcid":false,"given":"Mayreli","family":"Ortiz","sequence":"first","affiliation":[{"name":"Departament d'Enginyeria Qu\u00edmica Universitat Rovira i Virgili  Avinguda Pa\u00efsos Catalans 26 43007 Tarragona Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4346-529X","authenticated-orcid":false,"given":"Ahmed M.","family":"Debela","sequence":"additional","affiliation":[{"name":"Sorbonne Universit\u00e9, CNRS Institut Parisien de Chimie Mol\u00e9culaire IPCM  4 place Jussieu 75005 Paris France"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3296-8430","authenticated-orcid":false,"given":"Christophe","family":"M\u00e9thivier","sequence":"additional","affiliation":[{"name":"Sorbonne Universit\u00e9, CNRS Laboratoire de R\u00e9activit\u00e9 de Surface LRS  75005 Paris France"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0290-2820","authenticated-orcid":false,"given":"Serge","family":"Thorimbert","sequence":"additional","affiliation":[{"name":"Sorbonne Universit\u00e9, CNRS Institut Parisien de Chimie Mol\u00e9culaire IPCM  4 place Jussieu 75005 Paris France"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2518-1405","authenticated-orcid":false,"given":"Bernold","family":"Hasenknopf","sequence":"additional","affiliation":[{"name":"Sorbonne Universit\u00e9, CNRS Institut Parisien de Chimie Mol\u00e9culaire IPCM  4 place Jussieu 75005 Paris France"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2603-2230","authenticated-orcid":false,"given":"Ciara K.","family":"O'Sullivan","sequence":"additional","affiliation":[{"name":"Departament d'Enginyeria Qu\u00edmica Universitat Rovira i Virgili  Avinguda Pa\u00efsos Catalans 26 43007 Tarragona Spain"},{"name":"ICREA, Passeig Lluis Companys 23  08010 Barcelona Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2018,7,2]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1038\/35057149"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1101\/gr.7.6.606"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.forsciint.2004.10.020"},{"key":"e_1_2_7_5_2","first-page":"107","volume":"297","author":"Sobrino B.","year":"2005","journal-title":"Methods Mol. 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