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The reactions of AuCl(tht) with the phosphanyl\u2010 and arsanylboranes RR<jats:sup>\u2032<\/jats:sup>EBH<jats:sub>2<\/jats:sub>NMe<jats:sub>3<\/jats:sub> (E=P, As; R=H, Ph; R\u2032=H, Ph, <jats:italic>t<\/jats:italic>Bu) afford the complexes [AuCl(RR<jats:sup>\u2032<\/jats:sup>EBH<jats:sub>2<\/jats:sub>NMe<jats:sub>3<\/jats:sub>)]. In the solid state, [AuCl(H<jats:sub>2<\/jats:sub>PBH<jats:sub>2<\/jats:sub>NMe<jats:sub>3<\/jats:sub>)]<jats:sub>2<\/jats:sub> (<jats:bold>2\u2009a<\/jats:bold>) is a dimer showing unsupported intermolecular aurophilic interactions with short Au\u22c5\u22c5\u22c5Au distances. In contrast, [AuCl(H<jats:sub>2<\/jats:sub>AsBH<jats:sub>2<\/jats:sub>NMe<jats:sub>3<\/jats:sub>)]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub> (<jats:bold>2\u2009b<\/jats:bold>) aggregates to form 1D chains. Organic substituents on the pnictogen atoms lead to discrete molecules in [AuCl(RR<jats:sup>\u2032<\/jats:sup>PBH<jats:sub>2<\/jats:sub>NMe<jats:sub>3<\/jats:sub>)] (<jats:bold>2\u2009c<\/jats:bold>: R=H, R\u2032=<jats:italic>t<\/jats:italic>Bu; <jats:bold>2\u2009d<\/jats:bold>: R=R\u2032=Ph). To increase the aurophilicity, the ionic homoleptic complexes [Au(RR<jats:sup>\u2032<\/jats:sup>EBH<jats:sub>2<\/jats:sub>NMe<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>][AlCl<jats:sub>4<\/jats:sub>] (<jats:bold>3\u2009a<\/jats:bold>\u2013<jats:bold>d<\/jats:bold>) have been synthesized, for which <jats:bold>3\u2009a,b<\/jats:bold> form chains in the solid state and exhibit luminescence. The emissions show a drastic redshift with temperature decrease, correlating with decreasing Au\u22c5\u22c5\u22c5Au distances. DFT calculations provide insight into the bonding situation of the products.<\/jats:p>","DOI":"10.1002\/chem.201802682","type":"journal-article","created":{"date-parts":[[2018,5,29]],"date-time":"2018-05-29T21:55:25Z","timestamp":1527630925000},"page":"10073-10077","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":22,"title":["Gold(I) Complexes Containing Phosphanyl\u2010 and Arsanylborane Ligands"],"prefix":"10.1002","volume":"24","author":[{"given":"Jens","family":"Braese","sequence":"first","affiliation":[{"name":"Universit\u00e4t Regensburg Institut f\u00fcr Anorganische Chemie  94053 Regensburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alexander","family":"Schinabeck","sequence":"additional","affiliation":[{"name":"Universit\u00e4t Regensburg Institut f\u00fcr Physikalische Chemie  93053 Regensburg 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