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Its SHG response is about 12 times that of quartz. The compound crystallizes in the non\u2010centrosymmetric orthorhombic space group <jats:italic>Pna<\/jats:italic>2<jats:sub>1<\/jats:sub> with lattice parameters <jats:italic>a=<\/jats:italic>922.4(2), <jats:italic>b=<\/jats:italic>769.8(4), and <jats:italic>c=<\/jats:italic>1221.9(6)\u2005pm (<jats:italic>Z=<\/jats:italic>4). Characteristic for the structure are isolated B<jats:sub>3<\/jats:sub>O<jats:sub>7<\/jats:sub> moieties, consisting of two corner\u2010sharing BO<jats:sub>3<\/jats:sub> units and one BO<jats:sub>4<\/jats:sub> tetrahedron. These occupy half of the octahedral voids of a slightly distorted hexagonal closest packing of Sn<jats:sup>2+<\/jats:sup> atoms, with [SnF]<jats:sup>+<\/jats:sup> units in the other half of the octahedral voids. Sn<jats:sub>3<\/jats:sub>[B<jats:sub>3<\/jats:sub>O<jats:sub>7<\/jats:sub>]F is transparent over a wide spectral range with a UV cut\u2010off edge at about 263\u2005nm.<\/jats:p>","DOI":"10.1002\/chem.201803478","type":"journal-article","created":{"date-parts":[[2018,8,7]],"date-time":"2018-08-07T03:11:44Z","timestamp":1533611504000},"page":"16036-16043","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":26,"title":["Synthesis and Characterization of the First Tin Fluoride Borate Sn<sub>3<\/sub>[B<sub>3<\/sub>O<sub>7<\/sub>]F with Second Harmonic Generation Response"],"prefix":"10.1002","volume":"24","author":[{"given":"Sandra","family":"Sch\u00f6negger","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Allgemeine, Anorganische und Theoretische Chemie Leopold-Franzens-Universit\u00e4t Innsbruck  Innrain 80\u201382 6020 Innsbruck Austria"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Stephan G.","family":"Jantz","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Physik Universit\u00e4t Augsburg  Universit\u00e4tstr. 1 86159 Augsburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Andreas","family":"Saxer","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Konstruktion und Materialwissenschaften Leopold-Franzens-Universit\u00e4t Innsbruck  Technikerstra\u00dfe 13 6020 Innsbruck Austria"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lkhamsuren","family":"Bayarjargal","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Geowissenschaften Universit\u00e4t Frankfurt  Altenh\u00f6ferallee 1 60438 Frankfurt\/Main Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bj\u00f6rn","family":"Winkler","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Geowissenschaften Universit\u00e4t Frankfurt  Altenh\u00f6ferallee 1 60438 Frankfurt\/Main Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Florian","family":"Pielnhofer","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie Universit\u00e4t Regensburg  Universit\u00e4tsstra\u00dfe 31 93053 Regensburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Henning A.","family":"H\u00f6ppe","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Physik Universit\u00e4t Augsburg  Universit\u00e4tstr. 1 86159 Augsburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2098-6087","authenticated-orcid":false,"given":"Hubert","family":"Huppertz","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Allgemeine, Anorganische und Theoretische Chemie Leopold-Franzens-Universit\u00e4t Innsbruck  Innrain 80\u201382 6020 Innsbruck Austria"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2018,9,5]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.7.118"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201606782"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201606782"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-4095(199809)10:13<979::AID-ADMA979>3.0.CO;2-N"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1088\/0022-3727\/47\/25\/253001"},{"key":"e_1_2_7_5_1","first-page":"235","volume":"28","author":"Chen C. 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