{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T17:16:17Z","timestamp":1790529377106,"version":"4.1.0"},"reference-count":58,"publisher":"Wiley","issue":"55","license":[{"start":{"date-parts":[[2018,9,7]],"date-time":"2018-09-07T00:00:00Z","timestamp":1536278400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100000038","name":"Natural Sciences and Engineering Research Council of Canada","doi-asserted-by":"publisher","award":["RGPIN-2018-05531"],"award-info":[{"award-number":["RGPIN-2018-05531"]}],"id":[{"id":"10.13039\/501100000038","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2018,10]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A convenient synthesis of dicyanophosphide and dicyanoarsenide anions is reported. These heavy homologues of the long\u2010known and fundamentally important dicyanamide anion were formed through the nucleophilic displacement of bis(diphenylphosphino)ethane (dppe) from the pnictogen<jats:sup>+<\/jats:sup> transfer agents [dppePn][BPh<jats:sub>4<\/jats:sub>] (Pn=P, As) by exposure to cyanide salts. The protocol requires three synthetic steps from commercially available materials and the [dppePn][BPh<jats:sub>4<\/jats:sub>] salts are remarkably temperature, air, and moisture stable. All products have been fully characterized by spectroscopic methods and by single\u2010crystal X\u2010ray diffraction, and the electronic structures of the DCPn anions have been assessed computationally.<\/jats:p>","DOI":"10.1002\/chem.201803941","type":"journal-article","created":{"date-parts":[[2018,8,7]],"date-time":"2018-08-07T15:38:29Z","timestamp":1533656309000},"page":"14644-14648","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":24,"title":["Synthesis of Heavy Dicyanamide Homologues from Air\u2010Stable Precursors"],"prefix":"10.1002","volume":"24","author":[{"given":"Justin F.","family":"Binder","sequence":"first","affiliation":[{"name":"Department of Chemistry and Biochemistry University of Windsor  401 Sunset Ave. Windsor Ontario N9B 3P4 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stephanie C.","family":"Kosnik","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry University of Windsor  401 Sunset Ave. Windsor Ontario N9B 3P4 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"P. Blake J.","family":"St\u2005Onge","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry University of Windsor  401 Sunset Ave. Windsor Ontario N9B 3P4 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0574-1524","authenticated-orcid":false,"given":"Charles L. B.","family":"Macdonald","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry University of Windsor  401 Sunset Ave. Windsor Ontario N9B 3P4 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2018,9,7]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/jlac.19224270102"},{"key":"e_1_2_2_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1cc13979g"},{"key":"e_1_2_2_3_1","first-page":"103","volume":"4","author":"Stenger-Smith J. D.","year":"2009","journal-title":"Mater. Matters"},{"key":"e_1_2_2_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/ef800286b"},{"key":"e_1_2_2_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/b103064g"},{"key":"e_1_2_2_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/b205641k"},{"key":"e_1_2_2_7_1","first-page":"71","volume-title":"Magnetism: Molecules to Materials","author":"Manson J. L.","year":"2005"},{"key":"e_1_2_2_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(03)00119-X"},{"key":"e_1_2_2_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar0000354"},{"key":"e_1_2_2_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic3012958"},{"key":"e_1_2_2_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0dt01647k"},{"key":"e_1_2_2_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200300719"},{"key":"e_1_2_2_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.poly.2013.12.016"},{"key":"e_1_2_2_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.inoche.2011.01.035"},{"key":"e_1_2_2_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.inoche.2017.06.010"},{"key":"e_1_2_2_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm0607029"},{"key":"e_1_2_2_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2004.10.030"},{"key":"e_1_2_2_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200500479"},{"key":"e_1_2_2_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/a803165g"},{"key":"e_1_2_2_20_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.147.3665.1574"},{"key":"e_1_2_2_21_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.58.2.735"},{"key":"e_1_2_2_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/206707a0"},{"key":"e_1_2_2_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/0304-4165(66)90197-8"},{"key":"e_1_2_2_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja4115693"},{"key":"e_1_2_2_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja411667f"},{"key":"e_1_2_2_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201400762"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201400762"},{"key":"e_1_2_2_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.197909341"},{"key":"e_1_2_2_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19790911208"},{"key":"e_1_2_2_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19770891020"},{"key":"e_1_2_2_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/9780470132562.ch29"},{"key":"e_1_2_2_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19855270803"},{"key":"e_1_2_2_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201703317"},{"key":"e_1_2_2_32_1","doi-asserted-by":"publisher","DOI":"10.1515\/znb-1985-0613"},{"key":"e_1_2_2_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.201600270"},{"key":"e_1_2_2_34_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5DT03019F"},{"key":"e_1_2_2_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b01163"},{"key":"e_1_2_2_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC00331H"},{"key":"e_1_2_2_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic502229w"},{"key":"e_1_2_2_38_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5DT03915K"},{"key":"e_1_2_2_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2012.08.006"},{"key":"e_1_2_2_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2006.07.007"},{"key":"e_1_2_2_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/0277-5387(96)00200-8"},{"key":"e_1_2_2_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19931260309"},{"key":"e_1_2_2_43_1","doi-asserted-by":"publisher","DOI":"10.1039\/b302292g"},{"key":"e_1_2_2_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic049281s"},{"key":"e_1_2_2_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201301003"},{"key":"e_1_2_2_46_1","doi-asserted-by":"publisher","DOI":"10.1080\/10426500490427015"},{"key":"e_1_2_2_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/hc.1077"},{"key":"e_1_2_2_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20020201)41:3<450::AID-ANIE450>3.0.CO;2-N"},{"key":"e_1_2_2_48_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20020201)114:3<467::AID-ANGE467>3.0.CO;2-6"},{"key":"e_1_2_2_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic060186o"},{"key":"e_1_2_2_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200800987"},{"key":"e_1_2_2_51_1","doi-asserted-by":"publisher","DOI":"10.1039\/c002832k"},{"key":"e_1_2_2_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00082a031"},{"key":"e_1_2_2_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/zfch.19840241005"},{"key":"e_1_2_2_54_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19871200605"},{"key":"e_1_2_2_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.201500068"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.201803941","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201803941","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T14:17:28Z","timestamp":1760278648000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.201803941"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2018,9,7]]},"references-count":58,"journal-issue":{"issue":"55","published-print":{"date-parts":[[2018,10]]}},"alternative-id":["10.1002\/chem.201803941"],"URL":"https:\/\/doi.org\/10.1002\/chem.201803941","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2018,9,7]]},"assertion":[{"value":"2018-08-01","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2018-09-07","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}