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The compounds were characterized by 1<\/jats:sup>H, 13<\/jats:sup>C (1<\/jats:bold>\u201314<\/jats:bold>) and 119<\/jats:sup>Sn (7<\/jats:bold>\u201314<\/jats:bold>) NMR and IR spectroscopy, EIMS and single\u2010crystal XRD (2<\/jats:bold>, 7<\/jats:bold>\u201310<\/jats:bold> and 13<\/jats:bold>, 14<\/jats:bold>). Graph\u2010set analyses were performed for compounds [(MeNH(CMe2<\/jats:sub>CH2<\/jats:sub>OH)(CH2<\/jats:sub>CMe2<\/jats:sub>OH)][HC(O)O] (2\u2009a<\/jats:bold>) and 2<\/jats:bold>. The coordination environment about the tin(IV) centre of the spirocyclic compounds and their possible stereoisomers were analysed by DFT calculations (spiro<\/jats:italic>\u2010[MeN(CH2<\/jats:sub>CMe2<\/jats:sub>O)2<\/jats:sub>]2<\/jats:sub>Sn, 8<\/jats:bold>\u201310<\/jats:bold> and 13<\/jats:bold>).<\/jats:p>","DOI":"10.1002\/chem.201803952","type":"journal-article","created":{"date-parts":[[2018,10,13]],"date-time":"2018-10-13T12:45:06Z","timestamp":1539434706000},"page":"19266-19279","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Cis<\/i> versus Trans<\/i>: The Coordination Environment about the Tin(IV) Atom in Spirocyclic Amino Alcohol Derivatives"],"prefix":"10.1002","volume":"24","author":[{"given":"Britta","family":"Glowacki","sequence":"first","affiliation":[{"name":"Fakult\u00e4t f\u00fcr Chemie und Chemische Biologie Technische Universit\u00e4t Dortmund Otto-Hahn-Strasse 6 44227 Dortmund Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Roman","family":"Pallach","sequence":"additional","affiliation":[{"name":"Fakult\u00e4t f\u00fcr Chemie und Chemische Biologie Technische Universit\u00e4t Dortmund Otto-Hahn-Strasse 6 44227 Dortmund Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Michael","family":"Lutter","sequence":"additional","affiliation":[{"name":"Fakult\u00e4t f\u00fcr Chemie und Chemische Biologie Technische Universit\u00e4t Dortmund Otto-Hahn-Strasse 6 44227 Dortmund Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Fabian","family":"Roesler","sequence":"additional","affiliation":[{"name":"Fakult\u00e4t f\u00fcr Chemie und Chemische Biologie Technische Universit\u00e4t Dortmund Otto-Hahn-Strasse 6 44227 Dortmund Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hazem","family":"Alnasr","sequence":"additional","affiliation":[{"name":"Fakult\u00e4t f\u00fcr Chemie und Chemische Biologie Technische Universit\u00e4t Dortmund Otto-Hahn-Strasse 6 44227 Dortmund Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Cedreric","family":"Thomas","sequence":"additional","affiliation":[{"name":"Fakult\u00e4t f\u00fcr Chemie und Chemische Biologie Technische Universit\u00e4t Dortmund Otto-Hahn-Strasse 6 44227 Dortmund Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Dieter","family":"Schollmeyer","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Organische Chemie Johannes Gutenberg-Universit\u00e4t Mainz 55099 Mainz Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9930-858X","authenticated-orcid":false,"given":"Klaus","family":"Jurkschat","sequence":"additional","affiliation":[{"name":"Fakult\u00e4t f\u00fcr Chemie und Chemische Biologie Technische Universit\u00e4t Dortmund Otto-Hahn-Strasse 6 44227 Dortmund Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2018,11,28]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","first-page":"643","volume":"5","author":"Mehrotra R. 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