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Evaluating the factors that might limit <jats:italic>N<\/jats:italic>\u2010cyclisation pathways led to effective gold\u2010catalysed conditions that allow access to different fused \u03b3\u2010lactams on changing the ynamide <jats:italic>N<\/jats:italic>\u2010substituent and accommodate previously incompatible substitution patterns. New and efficient methods for the synthesis of functionalised 3\u2010aryl indoles and cyclohepta[c]pyrrol\u20101\u2010one derivatives are presented. These conditions illustrate the complementarity of gold catalysis to other metals.<\/jats:p>","DOI":"10.1002\/chem.201804378","type":"journal-article","created":{"date-parts":[[2018,9,24]],"date-time":"2018-09-24T13:18:44Z","timestamp":1537795124000},"page":"17215-17219","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":47,"title":["A Gold Carbene Manifold to Prepare Fused \u03b3\u2010Lactams by Oxidative Cyclisation of Ynamides"],"prefix":"10.1002","volume":"24","author":[{"given":"Fernando","family":"S\u00e1nchez\u2010Cantalejo","sequence":"first","affiliation":[{"name":"School of Chemistry University of Birmingham  Birmingham UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0651-2758","authenticated-orcid":false,"given":"Joshua D.","family":"Priest","sequence":"additional","affiliation":[{"name":"School of Chemistry University of Birmingham  Birmingham 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