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MOFs\n                    <jats:bold>1<\/jats:bold>\n                    \u2013\n                    <jats:bold>4<\/jats:bold>\n                    emitted solid\u2010state blue or cyan fluorescence emissions at 447\u00b17\u2005nm, which mainly arose from NI\u2010bpy\u201044 and are dependent on the incorporated solvents. After immersing the crystalline samples in different solvents, that is, H\n                    <jats:sub>2<\/jats:sub>\n                    O and DMSO (\n                    <jats:bold>1<\/jats:bold>\n                    and\n                    <jats:bold>2<\/jats:bold>\n                    ) as well as nitrobenzene and phenol (\n                    <jats:bold>1<\/jats:bold>\n                    \u2013\n                    <jats:bold>4<\/jats:bold>\n                    ), they exhibited a remarkable fluorescence quenching effect, whereas\n                    <jats:italic>o<\/jats:italic>\n                    \u2010xylene and\n                    <jats:italic>p<\/jats:italic>\n                    \u2010xylene (\n                    <jats:bold>4<\/jats:bold>\n                    ) caused significant fluorescence enhancement. The sensing ability of MOFs\n                    <jats:bold>1<\/jats:bold>\n                    \u2013\n                    <jats:bold>4<\/jats:bold>\n                    toward nitro compounds carried out in the vapor phase showed that nitrobenzene and 2\u2010nitrophenol displayed detectable fluorescence quenching with\n                    <jats:bold>1<\/jats:bold>\n                    ,\n                    <jats:bold>2<\/jats:bold>\n                    , and\n                    <jats:bold>4<\/jats:bold>\n                    whereas 4\u2010nitrotoluene was an effective fluorescence quencher for\n                    <jats:bold>1<\/jats:bold>\n                    and\n                    <jats:bold>2<\/jats:bold>\n                    ; this is most likely attributed to their electron\u2010deficient properties and higher vapor pressures. Moreover, MOFs\n                    <jats:bold>1<\/jats:bold>\n                    \u2013\n                    <jats:bold>4<\/jats:bold>\n                    are highly reusable for quick capture of volatile iodine, as supported by clear crystal color change and also by immense fluorescence quenching responses owing to the donor\u2013acceptor interaction. Low\u2010pressure CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorption isotherms indicate that activated materials\n                    <jats:bold>1\u2032<\/jats:bold>\n                    \u2013\n                    <jats:bold>4\u2032<\/jats:bold>\n                    are inefficient at taking up CO\n                    <jats:sub>2<\/jats:sub>\n                    .\n                  <\/jats:p>","DOI":"10.1002\/chem.201804673","type":"journal-article","created":{"date-parts":[[2018,11,4]],"date-time":"2018-11-04T22:05:50Z","timestamp":1541369150000},"page":"1337-1344","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":31,"title":["Fluorescent Cadmium Bipillared\u2010Layer Open Frameworks: Synthesis, Structures, Sensing of Nitro Compounds, and Capture of Volatile Iodine"],"prefix":"10.1002","volume":"25","author":[{"given":"Tang\u2010Ching","family":"Chen","sequence":"first","affiliation":[{"name":"Department of Applied Chemistry National Chi Nan University  Nantou 545 Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meng\u2010Jung","family":"Tsai","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry National Chi Nan University  Nantou 545 Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7257-4711","authenticated-orcid":false,"given":"Jing\u2010Yun","family":"Wu","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry National Chi Nan University  Nantou 545 Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2018,12,20]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00930A"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00010B"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr200324t"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.7b00918"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7DT03876C"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.7b00575"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.6b01755"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.7b01758"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7TA05896A"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b02810"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.7b01155"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.7b03914"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja407778a"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5TC01287B"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b01688"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201600184"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b09167"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.5b12062"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC05571C"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3TA14199C"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja106851d"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200804853"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200804853"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc46530f"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201304692"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2jm32066e"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4TC01982B"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3dt51450a"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.7b00536"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.7b00777"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3TA13983B"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.7b02264"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC09566F"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3dt50238d"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1cc00047k"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1039\/c4ce00028e"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201402211"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja211381e"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1cc11402f"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc34196d"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja204757x"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja2085096"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm401762g"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4TA01749H"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja908293n"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1039\/B210740F"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.8b02651"},{"key":"e_1_2_7_47_1","first-page":"702496","author":"Soelberg 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