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Specifically, no stable example of monomeric stannabenzene, that is, the tin analogue of benzene, the simplest aromatic compound, has been isolated until now. In this work, a tin analogue of the phenyl anion, the stannabenzenyl anion, was successfully isolated by utilizing the same strategy as employed for the germanium system. Stannabenzenylpotassium was characterized by X\u2010ray crystallography, NMR (<jats:sup>1<\/jats:sup>H, <jats:sup>13<\/jats:sup>C, and <jats:sup>119<\/jats:sup>Sn) and UV\/Vis spectroscopy, together with theoretical calculations.<\/jats:p>","DOI":"10.1002\/chem.201804858","type":"journal-article","created":{"date-parts":[[2018,10,19]],"date-time":"2018-10-19T11:09:17Z","timestamp":1539947357000},"page":"17039-17045","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":39,"title":["Stannabenzenylpotassium: The First Isolable Tin\u2010Containing Benzene Derivative"],"prefix":"10.1002","volume":"24","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8244-3096","authenticated-orcid":false,"given":"Shiori","family":"Fujimori","sequence":"first","affiliation":[{"name":"Institute for Chemical Research Kyoto University  Gokasho, Uji Kyoto 611-0011 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5301-0024","authenticated-orcid":false,"given":"Yoshiyuki","family":"Mizuhata","sequence":"additional","affiliation":[{"name":"Institute for Chemical Research Kyoto University  Gokasho, Uji Kyoto 611-0011 Japan"},{"name":"Integrated Research Consortium on Chemical Sciences  Gokasho, Uji Kyoto 611-0011 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1083-7245","authenticated-orcid":false,"given":"Norihiro","family":"Tokitoh","sequence":"additional","affiliation":[{"name":"Institute for Chemical Research Kyoto University  Gokasho, Uji Kyoto 611-0011 Japan"},{"name":"Integrated Research Consortium on Chemical Sciences  Gokasho, Uji Kyoto 611-0011 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2018,11,19]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/9780470669266"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/b800580j"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200604869"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200604869"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar020093k"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)00438-1"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2011.10.020"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2004.08.004"},{"key":"e_1_2_7_8_1","doi-asserted-by":"crossref","first-page":"619","DOI":"10.1016\/B978-0-12-801981-8.00010-1","volume-title":"Organosilicon Compd. 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