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The covalent grafting of 4,4,5,5\u2010tetramethyl\u20101,3,2\u2010dioxaborolane (BPin) functional groups directly on the surface of multi\u2010 and single\u2010walled carbon nanotubes, activated by nucleophilic addition of <jats:italic>n<\/jats:italic>BuLi, was carried out. Thermogravimetric analysis (TGA) coupled with mass spectrometry, Raman spectroscopy, X\u2010ray photoelectron spectroscopy (XPS) and time\u2010of\u2010flight secondary ions mass spectrometry (ToF\u2010SIMS) confirmed the efficiency of this methodology and proved the integrity and covalent grafting of the BPin functional groups. These groups were further reacted with various nucleophiles in the presence of a copper(II) source in the conditions of the aerobic Chan\u2013Lam\u2013Evans coupling. The resulting materials were characterized by TGA, XPS and ToF\u2010SIMS. This route is efficient, reliable and among the scarce reactions that enable the direct grafting of heteroatoms at carbonaceous material surfaces.<\/jats:p>","DOI":"10.1002\/chem.201804859","type":"journal-article","created":{"date-parts":[[2018,10,16]],"date-time":"2018-10-16T05:50:27Z","timestamp":1539669027000},"page":"1436-1440","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Covalent Grafting of BPin functions on Carbon Nanotubes and Chan\u2013Lam\u2013Evans Post\u2010Functionalization"],"prefix":"10.1002","volume":"25","author":[{"given":"Antonin","family":"Desmecht","sequence":"first","affiliation":[{"name":"Institute of Condensed Matter and Nanosciences, Molecules, Solids and Reactivity (IMCN\/MOST) Universit\u00e9 Catholique de Louvain  Place Louis Pasteur 1 1348 Louvain-la-Neuve 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