{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T01:13:57Z","timestamp":1788398037333,"version":"build-2803163510"},"reference-count":46,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2018,11,26]],"date-time":"2018-11-26T00:00:00Z","timestamp":1543190400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["SCHA1915\/3-1"],"award-info":[{"award-number":["SCHA1915\/3-1"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100007215","name":"Verband der Chemischen Industrie","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100007215","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100004349","name":"BASF","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100004349","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2019,1,2]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Permethylated disila[2]metallocenophanes of silicon, germanium, tin, lead, <jats:bold>2\u2009a<\/jats:bold>\u2013<jats:bold>d<\/jats:bold>, (tetrelocenophanes) and antimony, <jats:bold>3\u2009a<\/jats:bold>,<jats:bold>b<\/jats:bold>, (pnictogenocenophanes) are described. In the case of antimony, a chloro\u2010substituted stibonocenophane, <jats:bold>3\u2009a<\/jats:bold>, as well as cationic stibonocenophanium tetrachloroaluminate and tetraphenylborate salts, <jats:bold>3\u2009b<\/jats:bold>[X] (X=[AlCl<jats:sub>4<\/jats:sub>], [BPh<jats:sub>4<\/jats:sub>]), were synthesized. These represent the first examples of metallocenophanes of any Group 15 element. All compounds were studied in solution and in the solid state. Without exception the <jats:italic>ansa<\/jats:italic>\u2010bridge exerts a strong influence on the bending angle of the two Cp\u2010ligands. For disila[2]plumbocenophane, <jats:bold>2\u2009d<\/jats:bold>, its reactivity towards Group 15 halides was probed. Treatment of disila[2]plumbocenophane, <jats:bold>2\u2009d<\/jats:bold>, with two equivalents of phosphorus(III) chloride or arsenic(III) chloride, results in a ring\u2010opening reaction and gives the bis(dihalopnictogenyl)\u2010substituted products, <jats:bold>4\u2009a<\/jats:bold>,<jats:bold>b<\/jats:bold>.<\/jats:p>","DOI":"10.1002\/chem.201804934","type":"journal-article","created":{"date-parts":[[2018,10,31]],"date-time":"2018-10-31T06:25:45Z","timestamp":1540967145000},"page":"173-176","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Permethylated Disila[2]metallocenophanes of Group 14 and 15 Elements"],"prefix":"10.1002","volume":"25","author":[{"given":"Angelika S. D.","family":"Stahlich","sequence":"first","affiliation":[{"name":"Emmy Noether Research Group Faculty of Natural Sciences and Technology Saarland University, Campus Saarbr\u00fccken  66123 Saarbr\u00fccken Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Volker","family":"Huch","sequence":"additional","affiliation":[{"name":"Emmy Noether Research Group Faculty of Natural Sciences and Technology Saarland University, Campus Saarbr\u00fccken  66123 Saarbr\u00fccken Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexander","family":"Grandjean","sequence":"additional","affiliation":[{"name":"Emmy Noether Research Group Faculty of Natural Sciences and Technology Saarland University, Campus Saarbr\u00fccken  66123 Saarbr\u00fccken Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kevin","family":"Rohe","sequence":"additional","affiliation":[{"name":"Emmy Noether Research Group Faculty of Natural Sciences and Technology Saarland University, Campus Saarbr\u00fccken  66123 Saarbr\u00fccken Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kinga I.","family":"Leszczy\u0144ska","sequence":"additional","affiliation":[{"name":"Krupp Chair of General and Inorganic Chemistry Faculty of Natural Sciences and Technology Saarland University, Campus Saarbr\u00fccken  66123 Saarbr\u00fccken Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5600-8034","authenticated-orcid":false,"given":"David","family":"Scheschkewitz","sequence":"additional","affiliation":[{"name":"Krupp Chair of General and Inorganic Chemistry Faculty of Natural Sciences and Technology Saarland University, Campus Saarbr\u00fccken  66123 Saarbr\u00fccken Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5969-6618","authenticated-orcid":false,"given":"Andr\u00e9","family":"Sch\u00e4fer","sequence":"additional","affiliation":[{"name":"Emmy Noether Research Group Faculty of Natural Sciences and Technology Saarland University, Campus Saarbr\u00fccken  66123 Saarbr\u00fccken Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2018,11,26]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(20000103)39:1<123::AID-ANIE123>3.0.CO;2-Z"},{"key":"e_1_2_2_2_3","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(20000103)112:1<127::AID-ANGE127>3.0.CO;2-2"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/jr9520000632"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01128a527"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1038\/1681039b0"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19532740603"},{"key":"e_1_2_2_7_1","unstructured":"\u00a0"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01569a084"},{"key":"e_1_2_2_9_2","first-page":"438","volume":"70","author":"L\u00fcttringhaus A.","year":"1958","journal-title":"Angew. 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See reference [6f]."},{"key":"e_1_2_2_38_1","doi-asserted-by":"publisher","DOI":"10.1139\/v02-075"},{"key":"e_1_2_2_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19891220906"},{"key":"e_1_2_2_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/om060051q"},{"key":"e_1_2_2_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19801130233"},{"key":"e_1_2_2_42_1","doi-asserted-by":"publisher","DOI":"10.1039\/c39810000925"},{"key":"e_1_2_2_43_1","unstructured":"DFT calculations of NMR chemical shifts were performed at the GIAO M06-L\/IGLO-III(C H Cl P Si);TZ2P(As Ge Sb Sn);Def2-TZVPP(Pb)\/\/ B3LYP-D3\/6\u2013311+G(d p)(C H As Cl Ge P Sb Si);SDD(Pb Sb Sn) level of theory vs. SiMe4 using the Gaussian\u200509 Revision D.01 package of programs. 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