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The change in solvation results in changes in the structure and luminescence of the digold cation. The cation consists of a pair of slightly bent As\u2010Au\u2010As units that are connected through the two bridging dpae ligands and by aurophilic interactions with Au\u22c5\u22c5\u22c5Au contacts of 3.05152(15)\u2005\u00c5 in the disolvate or 2.9570(5)\u2005\u00c5 in the monosolvate.<\/jats:p>","DOI":"10.1002\/chem.201804937","type":"journal-article","created":{"date-parts":[[2018,10,24]],"date-time":"2018-10-24T22:16:37Z","timestamp":1540419397000},"page":"874-878","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":24,"title":["Vapoluminescent Behavior and the Single\u2010Crystal\u2010to\u2010Single\u2010Crystal Transformations of Chloroform Solvates of [Au<sub>2<\/sub>(\u03bc\u20101,2\u2010bis(diphenylarsino)ethane)<sub>2<\/sub>](AsF<sub>6<\/sub>)<sub>2<\/sub>"],"prefix":"10.1002","volume":"25","author":[{"given":"Kellie R.","family":"England","sequence":"first","affiliation":[{"name":"Department of Chemistry University of California, Davis  One Shields Avenue Davis CA 95616 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sang Ho","family":"Lim","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of California, Davis  One Shields Avenue Davis CA 95616 USA"},{"name":"Nuclear Chemistry Research Division Korea Atomic Energy Research Institute  111 Daedeok-daero 989beon-gil Yuseong-gu Daejeon 34057 Republic of Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lucy M. 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