{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,12,5]],"date-time":"2025-12-05T12:17:14Z","timestamp":1764937034571,"version":"build-2065373602"},"reference-count":68,"publisher":"Wiley","issue":"9","license":[{"start":{"date-parts":[[2019,1,21]],"date-time":"2019-01-21T00:00:00Z","timestamp":1548028800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","award":["16H04138","H18J15153"],"award-info":[{"award-number":["16H04138","H18J15153"]}],"id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2019,2,11]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Bis\u2010phosphanated compounds are regarded as the most ubiquitous privileged ligand structures in transition\u2010metal catalysis. The development of highly atom economical reactions is of great importance for their syntheses because less atom economical methods often require complicated purification procedures under inert atmospheres to remove excess starting materials and byproducts. Herein, the photoinduced addition reactions of diphosphane monosulfides bearing P<jats:sup>V<\/jats:sup>(S)\u2212P<jats:sup>III<\/jats:sup> single bonds to alkenes is disclosed. These reactions require only equimolar amounts of the diphosphane monosulfide relative to the alkene and facilitate highly selective introduction of two different types of phosphorus\u2010containing groups, such as thiophosphoryl and phosphanyl groups, into a variety of alkenes without any catalyst, base, or additive.<\/jats:p>","DOI":"10.1002\/chem.201805114","type":"journal-article","created":{"date-parts":[[2018,11,6]],"date-time":"2018-11-06T11:28:29Z","timestamp":1541503709000},"page":"2295-2302","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":31,"title":["Synthesis of Bis(phosphanyl)alkane Monosulfides by the Addition of Diphosphane Monosulfides to Alkenes under Light"],"prefix":"10.1002","volume":"25","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7778-2827","authenticated-orcid":false,"given":"Yuki","family":"Sato","sequence":"first","affiliation":[{"name":"Department of Applied Chemistry Graduate School of Engineering Osaka Prefecture University  1-1 Gakuen-cho, Nakaku Sakai, Osaka 599-8531 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4140-9959","authenticated-orcid":false,"given":"Shin\u2010ichi","family":"Kawaguchi","sequence":"additional","affiliation":[{"name":"Center for Education and Research in Agricultural Innovation Faculty of Agriculture Saga University  152-1 Shonan-cho Karatsu Saga 847-0021 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3427-2234","authenticated-orcid":false,"given":"Akihiro","family":"Nomoto","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry Graduate School of Engineering Osaka Prefecture University  1-1 Gakuen-cho, Nakaku Sakai, Osaka 599-8531 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8543-2560","authenticated-orcid":false,"given":"Akiya","family":"Ogawa","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry Graduate School of Engineering Osaka Prefecture University  1-1 Gakuen-cho, Nakaku Sakai, Osaka 599-8531 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2019,1,21]]},"reference":[{"volume-title":"A Guide to Organophosphorus Chemistry","year":"2000","author":"Quin L. 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This result shows that the homolytic cleavage of the P(S)\u2212P single bond in4\u2009aunder photoirradiation condition is highly reversible."},{"key":"e_1_2_7_54_1","unstructured":"When a mixture of diphosphane monosulfide4\u2009a(0.4\u2005mmol) and4\u2009e[(p-tol)2P(S)-P(p-tol)2 0.4\u2005mmol Table\u20053] dissolved in CD2Cl2(0.6\u2005mL) was irradiated with a xenon lamp (500\u2005W) for 4\u2005h four diphosphane monosulfides and other compounds were observed by31P\u2005NMR spectroscopy: Ph2P(S)PPh2(4\u2009a 26\u2009%) (p-tol)2P(S)P(p-tol)2(4\u2009e 26\u2009%) Ph2P(S)P(p-tol)2(17\u2009%) (p-tol)2P(S)PPh2(16\u2009%) and others (14\u2009%)."},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1039\/b807695b"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(97)01365-8"},{"key":"e_1_2_7_57_1","unstructured":"For other PdII\/bis-phosphane monosulfide complexes see:"},{"key":"e_1_2_7_58_2","doi-asserted-by":"publisher","DOI":"10.1021\/om020682u"},{"key":"e_1_2_7_59_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2006.03.024"},{"key":"e_1_2_7_60_2","doi-asserted-by":"publisher","DOI":"10.1021\/om500573q"},{"key":"e_1_2_7_61_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5b01490"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.201805114","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/am-pdf\/10.1002%2Fchem.201805114","content-type":"application\/pdf","content-version":"am","intended-application":"syndication"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201805114","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T17:04:49Z","timestamp":1760288689000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.201805114"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,1,21]]},"references-count":68,"journal-issue":{"issue":"9","published-print":{"date-parts":[[2019,2,11]]}},"alternative-id":["10.1002\/chem.201805114"],"URL":"https:\/\/doi.org\/10.1002\/chem.201805114","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"type":"print","value":"0947-6539"},{"type":"electronic","value":"1521-3765"}],"subject":[],"published":{"date-parts":[[2019,1,21]]},"assertion":[{"value":"2018-10-10","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2019-01-21","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}