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The borole group was successfully installed via the tin\u2013boron exchange reaction of 1,1\u2010dimethyl\u20102,3,4,5\u2010tetraphenylstannole with 9\u2010(5\u2010(dibromoboryl)thiophen\u20102\u2010yl)carbazole. The effect of the borole on the optoelectronic properties of the donor\u2013acceptor system was explored by spectroscopic (UV\/Vis and fluorescence spectroscopy), electrochemical (cyclic voltammetry) and theoretical (TD\u2010DFT) methods as well as by modifying its structure. The corresponding donor\u2013acceptor compound bearing the widely employed dimesitylboryl acceptor group was also synthesized for comparison.<\/jats:p>","DOI":"10.1002\/chem.201805454","type":"journal-article","created":{"date-parts":[[2019,2,20]],"date-time":"2019-02-20T17:52:01Z","timestamp":1550685121000},"page":"4707-4712","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":23,"title":["Preparation and Characterization of a \u03c0\u2010Conjugated Donor\u2013Acceptor System Containing the Strongly Electron\u2010Accepting Tetraphenylborolyl Unit"],"prefix":"10.1002","volume":"25","author":[{"given":"Michael","family":"Meier","sequence":"first","affiliation":[{"name":"Institute of Inorganic Chemistry Julius-Maximilians-Universit\u00e4t W\u00fcrzburg, Am Hubland, 97074 W\u00fcrzburg (Germany), and Institute for Sustainable Chemistry &amp; Catalysis with Boron, Julius-Maximilians-Universit\u00e4t W\u00fcrzburg  Am Hubland 97074 W\u00fcrzburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lei","family":"Ji","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry Julius-Maximilians-Universit\u00e4t W\u00fcrzburg, Am Hubland, 97074 W\u00fcrzburg (Germany), and Institute for Sustainable Chemistry &amp; 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