{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T12:31:56Z","timestamp":1790512316429,"version":"4.1.0"},"reference-count":96,"publisher":"Wiley","issue":"6","license":[{"start":{"date-parts":[[2019,1,7]],"date-time":"2019-01-07T00:00:00Z","timestamp":1546819200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2019,1,28]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The allosteric control of the receptor properties of two flexible covalent cages is reported. These receptors consist of two zinc(II) porphyrins connected by four linkers of two different sizes, each incorporating two 1,2,3\u2010triazolyl ligands. Silver(I) ions act as effectors, responsible for an on\/off encapsulation mechanism of neutral guest molecules. Binding silver(I) ions to the triazoles opens the cages and triggers the coordination of pyrazine or the encapsulation of\n                    <jats:italic>N<\/jats:italic>\n                    ,\n                    <jats:italic>N<\/jats:italic>\n                    \u2032\u2010dibutyl\u20101,4,5,8\u2010naphthalene diimide. The X\u2010ray structure of the silver(I)\u2010complexed receptor with short connectors is reported, revealing the hollow structure with a cavity well\u2010defined by two eclipsed porphyrins. Rather unexpectedly, the crystallographic structure of this receptor with pyrazine as a guest molecule showed that the cavity is occupied by two pyrazines, each binding to the zinc(II) porphyrin in a monotopic fashion.\n                  <\/jats:p>","DOI":"10.1002\/chem.201805498","type":"journal-article","created":{"date-parts":[[2018,12,10]],"date-time":"2018-12-10T07:09:32Z","timestamp":1544425772000},"page":"1481-1487","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":33,"title":["Positive Allosteric Control of Guests Encapsulation by Metal Binding to Covalent Porphyrin Cages"],"prefix":"10.1002","volume":"25","author":[{"given":"Ryan","family":"Djemili","sequence":"first","affiliation":[{"name":"Laboratoire de Synth\u00e8se des Assemblages Mol\u00e9culaires Multifonctionnels Institut de Chimie de Strasbourg, CNRS\/UMR 7177 Universit\u00e9 de Strasbourg  4, rue Blaise Pascal 67000 Strasbourg France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lucas","family":"Kocher","sequence":"additional","affiliation":[{"name":"Laboratoire de Synth\u00e8se des Assemblages Mol\u00e9culaires Multifonctionnels Institut de Chimie de Strasbourg, CNRS\/UMR 7177 Universit\u00e9 de Strasbourg  4, rue Blaise Pascal 67000 Strasbourg France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8815-0422","authenticated-orcid":false,"given":"St\u00e9phanie","family":"Durot","sequence":"additional","affiliation":[{"name":"Laboratoire de Synth\u00e8se des Assemblages Mol\u00e9culaires Multifonctionnels Institut de Chimie de Strasbourg, CNRS\/UMR 7177 Universit\u00e9 de Strasbourg  4, rue Blaise Pascal 67000 Strasbourg France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anssi","family":"Peuronen","sequence":"additional","affiliation":[{"name":"Inorganic Materials Chemistry Research Group, Laboratory of Materials Chemistry and Chemical Analysis Department of Chemistry University of Turku  20014 Turku Finland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kari","family":"Rissanen","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Jyvaskyla  40014 Jyv\u00e4skyl\u00e4 Finland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5828-9199","authenticated-orcid":false,"given":"Val\u00e9rie","family":"Heitz","sequence":"additional","affiliation":[{"name":"Laboratoire de Synth\u00e8se des Assemblages Mol\u00e9culaires Multifonctionnels Institut de Chimie de Strasbourg, CNRS\/UMR 7177 Universit\u00e9 de Strasbourg  4, rue Blaise Pascal 67000 Strasbourg France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2019,1,7]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cell.2016.08.015"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr4005082"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.bbapap.2010.10.008"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00191E"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar9001203"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr200077m"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc43191f"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3CC49192G"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar040152p"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200805340"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200805340"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00192C"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00211C"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00165F"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00157E"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00273C"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b01776"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3CS60037H"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/B614961H"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr4001226"},{"key":"e_1_2_6_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b02745"},{"key":"e_1_2_6_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b08976"},{"key":"e_1_2_6_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201705303"},{"key":"e_1_2_6_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b11679"},{"key":"e_1_2_6_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2016.11.004"},{"key":"e_1_2_6_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6OB01303A"},{"key":"e_1_2_6_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr030673a"},{"key":"e_1_2_6_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201203814"},{"key":"e_1_2_6_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar000177y"},{"key":"e_1_2_6_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b01054"},{"key":"e_1_2_6_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201000380"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201000380"},{"key":"e_1_2_6_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7SC04070A"},{"key":"e_1_2_6_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201806607"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201806607"},{"key":"e_1_2_6_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00106a010"},{"key":"e_1_2_6_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja5130379"},{"key":"e_1_2_6_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja503506a"},{"key":"e_1_2_6_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol9009392"},{"key":"e_1_2_6_37_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC02226F"},{"key":"e_1_2_6_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201311251"},{"key":"e_1_2_6_38_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201311251"},{"key":"e_1_2_6_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja064233n"},{"key":"e_1_2_6_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200603366"},{"key":"e_1_2_6_40_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200603366"},{"key":"e_1_2_6_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200462394"},{"key":"e_1_2_6_41_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200462394"},{"key":"e_1_2_6_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja501809s"},{"key":"e_1_2_6_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja504077f"},{"key":"e_1_2_6_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b00840"},{"key":"e_1_2_6_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201711077"},{"key":"e_1_2_6_45_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201711077"},{"key":"e_1_2_6_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201700395"},{"key":"e_1_2_6_47_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaf3673"},{"key":"e_1_2_6_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja028463n"},{"key":"e_1_2_6_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201509265"},{"key":"e_1_2_6_49_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201509265"},{"key":"e_1_2_6_50_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc30339f"},{"key":"e_1_2_6_51_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar500104k"},{"key":"e_1_2_6_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201207373"},{"key":"e_1_2_6_52_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201207373"},{"key":"e_1_2_6_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200400849"},{"key":"e_1_2_6_54_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc41369a"},{"key":"e_1_2_6_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201105374"},{"key":"e_1_2_6_55_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201105374"},{"key":"e_1_2_6_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol100770j"},{"key":"e_1_2_6_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201000146"},{"key":"e_1_2_6_57_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201000146"},{"key":"e_1_2_6_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja406893y"},{"key":"e_1_2_6_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr400673y"},{"key":"e_1_2_6_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja512637k"},{"key":"e_1_2_6_61_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b00283"},{"key":"e_1_2_6_62_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201705531"},{"key":"e_1_2_6_63_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b11523"},{"key":"e_1_2_6_64_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja052993c"},{"key":"e_1_2_6_65_1","doi-asserted-by":"publisher","DOI":"10.1071\/CH10221"},{"key":"e_1_2_6_66_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b12404"},{"key":"e_1_2_6_67_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201509108"},{"key":"e_1_2_6_67_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201509108"},{"key":"e_1_2_6_68_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201803873"},{"key":"e_1_2_6_68_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201803873"},{"key":"e_1_2_6_69_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja210418t"},{"key":"e_1_2_6_70_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja203491s"},{"key":"e_1_2_6_71_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4RA04583A"},{"key":"e_1_2_6_72_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja507531b"},{"key":"e_1_2_6_73_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3ob27481k"},{"key":"e_1_2_6_74_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b07494"},{"key":"e_1_2_6_75_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b08555"},{"key":"e_1_2_6_76_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201502152"},{"key":"e_1_2_6_77_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc31855e"},{"key":"e_1_2_6_78_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC04972E"},{"key":"e_1_2_6_79_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.7b00698"},{"key":"e_1_2_6_80_1","doi-asserted-by":"publisher","DOI":"10.1039\/b923211g"},{"key":"e_1_2_6_81_1","doi-asserted-by":"publisher","DOI":"10.1021\/j100823a036"},{"key":"e_1_2_6_82_1","volume-title":"CRC Handbook of Chemistry and Physics","author":"Rumble J.","year":"2018"},{"key":"e_1_2_6_83_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3765(19980615)4:6<1016::AID-CHEM1016>3.0.CO;2-B"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.201805498","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201805498","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201805498","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T16:27:02Z","timestamp":1760286422000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.201805498"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,1,7]]},"references-count":96,"journal-issue":{"issue":"6","published-print":{"date-parts":[[2019,1,28]]}},"alternative-id":["10.1002\/chem.201805498"],"URL":"https:\/\/doi.org\/10.1002\/chem.201805498","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2019,1,7]]},"assertion":[{"value":"2018-11-02","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2019-01-07","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}