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Both cluster ions chemisorbed methane as the major reaction channels at room temperature. [Al<jats:sub>2<\/jats:sub>VO<jats:sub>5<\/jats:sub>]<jats:sup>+<\/jats:sup> could break only one C\u2212H bond to liberate CH<jats:sub>3<\/jats:sub>, whereas [AlV<jats:sub>2<\/jats:sub>O<jats:sub>6<\/jats:sub>]<jats:sup>+<\/jats:sup> exhibited higher oxidizing ability such that it brings about the selective generation of formaldehyde. Mechanistic aspects are revealed and the crucial roles of the metal centers are discussed.<\/jats:p>","DOI":"10.1002\/chem.201805908","type":"journal-article","created":{"date-parts":[[2019,1,19]],"date-time":"2019-01-19T14:07:31Z","timestamp":1547906851000},"page":"2967-2971","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Tuning the Reactivities of the Heteronuclear [Al<sub><i>n<\/i><\/sub>V<sub>3\u2212<i>n<\/i><\/sub>O<sub>7\u2212<i>n<\/i><\/sub>]<sup>+<\/sup> (<i>n=<\/i>1,\u20052) Cluster Oxides towards Methane by Varying the Composition of the Metal Centers"],"prefix":"10.1002","volume":"25","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3048-4678","authenticated-orcid":false,"given":"Shaodong","family":"Zhou","sequence":"first","affiliation":[{"name":"Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology College of Chemical and Biological Engineering Zhejiang University  310027 Hangzhou P. 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