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The assignments for the major vibrational modes were confirmed by appropriate S<jats:sup>18<\/jats:sup>O<jats:sub>2<\/jats:sub> and <jats:sup>34<\/jats:sup>SO<jats:sub>2<\/jats:sub> isotopic shifts and density functional vibrational frequency calculations (B3LYP and BPW91). Interestingly, the mononuclear complexes are interconvertible; that is, irradiation induces the isomerization of Sn(<jats:italic>\u03b7<\/jats:italic><jats:sup>2<\/jats:sup>\u2010O<jats:sub>2<\/jats:sub>S) and Sn(<jats:italic>\u03b7<\/jats:italic><jats:sup>2<\/jats:sup>\u2010O<jats:sub>2<\/jats:sub>S)(<jats:italic>\u03b7<\/jats:italic><jats:sup>1<\/jats:sup>\u2010OSO) to Sn(<jats:italic>\u03b7<\/jats:italic><jats:sup>2<\/jats:sup>\u2010OSO) and Sn(<jats:italic>\u03b7<\/jats:italic><jats:sup>2<\/jats:sup>\u2010O<jats:sub>2<\/jats:sub>S)<jats:sub>2<\/jats:sub>, respectively, and vice versa on annealing. However, there is no evidence of isomerization reaction in between the binuclear molecules OSn<jats:sub>2<\/jats:sub>(<jats:italic>\u03b7<\/jats:italic><jats:sup>2<\/jats:sup>\u2010SO) and Sn(<jats:italic>\u03bc<\/jats:italic><jats:sub>2<\/jats:sub>\u2010O<jats:sub>2<\/jats:sub>)SnS. Bonding in these products is discussed, and the electronic structure changes associated with different bonding types are revealed, which is crucial for the observed photochemical reactions.<\/jats:p>","DOI":"10.1002\/chem.201806154","type":"journal-article","created":{"date-parts":[[2019,1,30]],"date-time":"2019-01-30T00:01:56Z","timestamp":1548806516000},"page":"5698-5707","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Photosensitive Tin Sulfur Dioxide Complexes with Unexpected Bonding Modes"],"prefix":"10.1002","volume":"25","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7285-2515","authenticated-orcid":false,"given":"Xing","family":"Liu","sequence":"first","affiliation":[{"name":"College of Chemistry and Chemical Engineering Southwest University  Chongqing 400715 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiao\u2010Rui","family":"Liu","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering Southwest University  Chongqing 400715 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2019,3,19]]},"reference":[{"key":"e_1_2_6_1_1","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/jz301158u"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1230911"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature11278"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1213229"},{"key":"e_1_2_6_6_1","unstructured":"\u00a0"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2012.02.025"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2011.09.070"},{"key":"e_1_2_6_9_1","unstructured":"\u00a0"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/B916550A"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0ee00616e"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja204808h"},{"key":"e_1_2_6_13_1","unstructured":"\u00a0"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201109109"},{"key":"e_1_2_6_14_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201109109"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(99)00191-5"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja303943q"},{"key":"e_1_2_6_17_1","unstructured":"\u00a0"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp982269z"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1088\/0953-8984\/9\/18\/006"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1cp21694e"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0039-6028(99)00287-3"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja982174a"},{"key":"e_1_2_6_23_1","unstructured":"\u00a0"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1063\/1674-0068\/26\/06\/747-754"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic3008987"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3cp51137e"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3cp53811g"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp5104998"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cplett.2013.04.037"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp9033408"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic900869f"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.6b08799"},{"key":"e_1_2_6_33_1","unstructured":"\u00a0"},{"key":"e_1_2_6_34_2","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.20130266"},{"key":"e_1_2_6_35_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature08634"},{"key":"e_1_2_6_36_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1176443"},{"key":"e_1_2_6_37_1","unstructured":"\u00a0"},{"key":"e_1_2_6_38_2","doi-asserted-by":"publisher","DOI":"10.1039\/b813442a"},{"key":"e_1_2_6_39_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja805358u"},{"key":"e_1_2_6_40_1","unstructured":"\u00a0"},{"key":"e_1_2_6_41_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja5006477"},{"key":"e_1_2_6_42_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b03306"},{"key":"e_1_2_6_43_1","unstructured":"\u00a0"},{"key":"e_1_2_6_44_2","doi-asserted-by":"publisher","DOI":"10.1021\/j100631a009"},{"key":"e_1_2_6_45_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1674155"},{"key":"e_1_2_6_46_1","doi-asserted-by":"publisher","DOI":"10.1039\/b915364k"},{"key":"e_1_2_6_47_1","unstructured":"\u00a0"},{"key":"e_1_2_6_48_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201002641"},{"key":"e_1_2_6_49_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201002584"},{"key":"e_1_2_6_50_2","doi-asserted-by":"publisher","DOI":"10.1039\/b919828h"},{"key":"e_1_2_6_51_1","doi-asserted-by":"publisher","DOI":"10.3891\/acta.chem.scand.36a-0429"},{"key":"e_1_2_6_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.6b00692"},{"key":"e_1_2_6_53_1","unstructured":"\u00a0"},{"key":"e_1_2_6_54_2","doi-asserted-by":"publisher","DOI":"10.1039\/b210547k"},{"key":"e_1_2_6_55_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr0000729"},{"key":"e_1_2_6_56_1","unstructured":"Gaussian\u200509 Revision\u2005C.01 M.\u2005J. 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