{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T17:37:38Z","timestamp":1791913058873,"version":"4.3.4"},"reference-count":49,"publisher":"Wiley","issue":"13","license":[{"start":{"date-parts":[[2019,2,4]],"date-time":"2019-02-04T00:00:00Z","timestamp":1549238400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100007215","name":"Verband der Chemischen Industrie","doi-asserted-by":"publisher","award":["Liebig Fellowship"],"award-info":[{"award-number":["Liebig Fellowship"]}],"id":[{"id":"10.13039\/100007215","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2019,3]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Syntheses of a bulky carbazole\u2010based substituent, the parent 1,8\u2010bis(3,5\u2010di\u2010<jats:italic>tert<\/jats:italic>\u2010butylphenyl)\u20103,6\u2010di\u2010<jats:italic>tert<\/jats:italic>\u2010butyl\u2010carbazole (R\u2212H) and a series of chlorotetrylenes, RECl (E=Ge, Sn, Pb), are described. Detailed analysis of the properties of the carbazole\u2010based substituent revealed that it features flexible high bulkiness and electronic non\u2010innocence, which may make it suitable for many applications in both main\u2010group and transition\u2010metal chemistry. To further showcase the employability of the novel substituent, the chlorotetrylenes were subjected to halide abstraction reactions, affording the corresponding tetrylenium salts [RE][Al(OC<jats:sub>4<\/jats:sub>F<jats:sub>9<\/jats:sub>)<jats:sub>4<\/jats:sub>] (E=Ge, Sn, Pb) as strongly coloured compounds.<\/jats:p>","DOI":"10.1002\/chem.201806346","type":"journal-article","created":{"date-parts":[[2019,2,5]],"date-time":"2019-02-05T04:36:32Z","timestamp":1549341392000},"page":"3267-3271","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":66,"title":["Pseudo\u2010One\u2010Coordinate Tetrylenium Salts Bearing a Bulky Carbazolyl Substituent"],"prefix":"10.1002","volume":"25","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7831-1410","authenticated-orcid":false,"given":"Alexander","family":"Hinz","sequence":"first","affiliation":[{"name":"Institute of Inorganic Chemistry (AOC) Karlsruhe Institute of Technology (KIT)  Engesserstr. 15, Geb\u00e4ude 30.45 76131 Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2019,2,4]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature08634"},{"key":"e_1_2_2_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1183281"},{"key":"e_1_2_2_3_1","doi-asserted-by":"publisher","DOI":"10.2174\/138527212803251604"},{"key":"e_1_2_2_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2015.12.057"},{"key":"e_1_2_2_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(03)00174-8"},{"key":"e_1_2_2_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/B716674E"},{"key":"e_1_2_2_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201406490"},{"key":"e_1_2_2_8_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1099879"},{"key":"e_1_2_2_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19801130233"},{"key":"e_1_2_2_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19891220512"},{"key":"e_1_2_2_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201402163"},{"key":"e_1_2_2_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja970196b"},{"key":"e_1_2_2_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200900222"},{"key":"e_1_2_2_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200602327"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200602327"},{"key":"e_1_2_2_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic0155582"},{"key":"e_1_2_2_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/om100712a"},{"key":"e_1_2_2_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/b702994b"},{"key":"e_1_2_2_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201508940"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201508940"},{"key":"e_1_2_2_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b02377"},{"key":"e_1_2_2_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200353365"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200353365"},{"key":"e_1_2_2_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201204601"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201204601"},{"key":"e_1_2_2_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja058188f"},{"key":"e_1_2_2_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/b301902k"},{"key":"e_1_2_2_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja4064469"},{"key":"e_1_2_2_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/om00018a041"},{"key":"e_1_2_2_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8SC02591F"},{"key":"e_1_2_2_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201303671"},{"key":"e_1_2_2_28_1","unstructured":"All three salts [7\u2009E][Al(OC4F9)4] crystallise with two ion pairs in the asymmetric unit. 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