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In this Concept article, a concise personal perspective on the recent advancements in the field of biomimetic catalytic models for methanol and formaldehyde conversion, in the presence and absence of enzymes and co\u2010factors, towards the formation of hydrogen under ambient conditions is given. In particular, formaldehyde dehydrogenase mimics have been introduced in stand\u2010alone C<jats:sub>1<\/jats:sub>\u2010interconversion networks. Recently, coupled systems with alcohol oxidase and dehydrogenase enzymes have been also developed for in situ formation and decomposition of formaldehyde and\/or reduced\/oxidized nicotinamide adenine dinucleotide (NADH\/ NAD<jats:sup>+<\/jats:sup>). Although C<jats:sub>1<\/jats:sub> molecules are already used in many industries for hydrogen production, these conceptual bioinspired low\u2010temperature energy conversion processes may lead one day to more efficient energy storage systems enabling renewable and sustainable hydrogen generation for hydrogen fuel cells under ambient conditions using C<jats:sub>1<\/jats:sub> molecules as fuels for mobile and miniaturized energy storage solutions in which harsh conditions like those in industrial plants are not applicable.<\/jats:p>","DOI":"10.1002\/chem.201806351","type":"journal-article","created":{"date-parts":[[2019,1,16]],"date-time":"2019-01-16T06:06:19Z","timestamp":1547618779000},"page":"6474-6481","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Chemoenzymatic Hydrogen Production from Methanol through the Interplay of Metal Complexes and Biocatalysts"],"prefix":"10.1002","volume":"25","author":[{"given":"Ghazal","family":"Tavakoli","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Cologne  Greinstr. 6 50939 K\u00f6ln Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jessica E.","family":"Armstrong","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Cologne  Greinstr. 6 50939 K\u00f6ln Germany"},{"name":"Department of Chemistry Yale University  225 Prospect St New Haven CT 06511-8499 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Janne M.","family":"Naapuri","sequence":"additional","affiliation":[{"name":"Department of Chemistry &amp; Materials Science Aalto University  Kemistintie 1 FI-02150 Espoo Finland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4622-2365","authenticated-orcid":false,"given":"Jan","family":"Deska","sequence":"additional","affiliation":[{"name":"Department of Chemistry &amp; Materials Science Aalto University  Kemistintie 1 FI-02150 Espoo Finland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2155-8006","authenticated-orcid":false,"given":"Martin H. 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