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In this respect, a synthetic method that is based on a reductive rearrangement and is capable of converting air\u2010stable pentavalent phosphorus compounds into reactive trivalent phosphorus compounds is a powerful tool. Tetraphenyldiphosphine disulfide, which is a shelf\u2010stable solid, was the focus of this study, and it was shown to undergo reductive rearrangement to trigger the bisthiophosphinylation of a variety of alkenes, such as terminal, cyclic, internal, and branched alkenes, 1,3\u2010dienes, and terminal alkynes when exposed to light without any catalyst, base, or additive.<\/jats:p>","DOI":"10.1002\/chem.201900073","type":"journal-article","created":{"date-parts":[[2019,3,8]],"date-time":"2019-03-08T12:03:52Z","timestamp":1552046632000},"page":"6797-6806","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":33,"title":["Reductive Rearrangement of Tetraphenyldiphosphine Disulfide To Trigger the Bisthiophosphinylation of Alkenes and Alkynes"],"prefix":"10.1002","volume":"25","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7778-2827","authenticated-orcid":false,"given":"Yuki","family":"Sato","sequence":"first","affiliation":[{"name":"Department of Applied Chemistry Graduate School of Engineering Osaka Prefecture University  1-1 Gakuen-cho, Nakaku Sakai, Osaka 599-8531 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Misaki","family":"Nishimura","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry Graduate School of Engineering Osaka Prefecture University  1-1 Gakuen-cho, Nakaku Sakai, Osaka 599-8531 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4140-9959","authenticated-orcid":false,"given":"Shin\u2010ichi","family":"Kawaguchi","sequence":"additional","affiliation":[{"name":"Center for Education and Research in Agricultural Innovation Faculty of Agriculture Saga University  152-1 Shonan-cho Karatsu Saga 847-0021 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3427-2234","authenticated-orcid":false,"given":"Akihiro","family":"Nomoto","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry Graduate School of Engineering Osaka Prefecture University  1-1 Gakuen-cho, Nakaku Sakai, Osaka 599-8531 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8543-2560","authenticated-orcid":false,"given":"Akiya","family":"Ogawa","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry Graduate School of Engineering Osaka Prefecture University  1-1 Gakuen-cho, Nakaku Sakai, Osaka 599-8531 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2019,4,25]]},"reference":[{"key":"e_1_2_7_1_1","volume-title":"A Guide to Organophosphorus Chemistry","author":"Quin L. 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