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The straightforward synthesis of one of these dimers is described and its properties have been investigated through UV\/Vis spectroscopy, cyclic voltammetry, differential scanning calorimetry, and charge\u2010carrier mobility measurements by using organic field\u2010effect transistors and space\u2013charge\u2010limited current diodes. The results allow a chemical strategy to decrease the tendency of \u03b1\u2010fused BODIPY to crystallize, to increase its light\u2010harvesting properties, and to promote isotropic charge carriers transport. Moreover, the disclosed approach is also a way to maintain the deep LUMO level of \u03b1\u2010fused BODIPY; thus making this class of materials highly desirable for optoelectronic applications.<\/jats:p>","DOI":"10.1002\/chem.201900536","type":"journal-article","created":{"date-parts":[[2019,3,19]],"date-time":"2019-03-19T05:08:04Z","timestamp":1552972084000},"page":"6613-6620","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":18,"title":["Pairing of \u03b1\u2010Fused BODIPY: Towards Panchromatic n\u2010Type Semiconducting Materials"],"prefix":"10.1002","volume":"25","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2888-9887","authenticated-orcid":false,"given":"Quentin","family":"Huaulm\u00e9","sequence":"first","affiliation":[{"name":"ICPEES-UMR7515 CNRS-Universit\u00e9 de Strasbourg  25 rue Becquerel 67087 Strasbourg CEDEX 02 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