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The P\u2212P bond in <jats:bold>1<\/jats:bold> can be broken via dismutation reactions with diaryl dichalcogenides yielding <jats:italic>nido<\/jats:italic>\u2010carboranyl bis\u2010phosphanes that were not accessible via established synthetic protocols. Additionally, transition metal complexes of <jats:bold>1<\/jats:bold> could be isolated including one coordination polymer. Notably, when the deboronation of <jats:bold>2<\/jats:bold> is carried out in ethanol, unprecedented <jats:italic>nido<\/jats:italic>\u2010carborane\u2010substituted secondary bis\u2010phosphane monoxides (<jats:bold>3<\/jats:bold>, <jats:bold>4<\/jats:bold>) are obtained. These compounds are interesting starting materials for further reactivity studies due to their P\u2212H bonds. Experimental findings are supported by DFT calculations including the calculation of reaction mechanisms and NMR spectroscopic parameters.<\/jats:p>","DOI":"10.1002\/chem.201900989","type":"journal-article","created":{"date-parts":[[2019,5,10]],"date-time":"2019-05-10T07:37:31Z","timestamp":1557473851000},"page":"11456-11465","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Accessing the First <i>nido<\/i>\u2010Carborane\u2010Substituted Diphosphetane: A\u2009Ligand and Synthon for <i>nido<\/i>\u2010Carboranylphosphanes"],"prefix":"10.1002","volume":"25","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1387-4148","authenticated-orcid":false,"given":"Peter","family":"Coburger","sequence":"first","affiliation":[{"name":"Leipzig University Faculty of Chemistry and Mineralogy Institute of Inorganic Chemistry  Johannisallee 29 04103 Leipzig Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8037-0591","authenticated-orcid":false,"given":"Pavlo","family":"Bielytskyi","sequence":"additional","affiliation":[{"name":"Leipzig University Faculty of Chemistry and Mineralogy Institute of Analytical Chemistry  Linn\u00e9stra\u00dfe 3 04103 Leipzig Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Darcy","family":"Williamson","sequence":"additional","affiliation":[{"name":"Leipzig University Faculty of Chemistry and Mineralogy Institute of Inorganic Chemistry  Johannisallee 29 04103 Leipzig Germany"},{"name":"Monash University  Wellington Rd Clayton VIC 3800 Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Evgeny","family":"Rys","sequence":"additional","affiliation":[{"name":"Leipzig University Faculty of Chemistry and Mineralogy Institute of Inorganic Chemistry  Johannisallee 29 04103 Leipzig Germany"},{"name":"A. 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