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The reaction of the dinuclear ytterbium(II) complex [Yb<jats:sub>2<\/jats:sub>L<jats:sub>4<\/jats:sub>], <jats:bold>1<\/jats:bold>, [L=(O<jats:italic>t<\/jats:italic>Bu)<jats:sub>3<\/jats:sub>SiO<jats:sup>\u2212<\/jats:sup>] with carbon disulfide led to the isolation of unprecedented reduction products. In particular, the crystallographic characterization of complex [Yb<jats:sub>2<\/jats:sub>L<jats:sub>4<\/jats:sub>(\u03bc\u2010C<jats:sub>2<\/jats:sub>S<jats:sub>2<\/jats:sub>)], <jats:bold>2<\/jats:bold>, provided the first example of an acetylenedithiolate ligand formed from metal reduction of CS<jats:sub>2<\/jats:sub>. Computational studies indicated that this unprecedented reactivity can be ascribed to the unusual binding mode of CS<jats:sub>2<\/jats:sub><jats:sup>2\u2212<\/jats:sup> in the isolated \u201ckey intermediate\u201d [Yb<jats:sub>2<\/jats:sub>L<jats:sub>4<\/jats:sub>(\u03bc\u2010CS<jats:sub>2<\/jats:sub>)], <jats:bold>3<\/jats:bold>, which results from the dinuclear nature of <jats:bold>1<\/jats:bold>.<\/jats:p>","DOI":"10.1002\/chem.201901321","type":"journal-article","created":{"date-parts":[[2019,4,8]],"date-time":"2019-04-08T10:26:31Z","timestamp":1554719191000},"page":"7831-7834","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["CS<sub>2<\/sub> Reductive Coupling to Acetylenedithiolate by a Dinuclear Ytterbium(II) Complex"],"prefix":"10.1002","volume":"25","author":[{"given":"Davide","family":"Toniolo","sequence":"first","affiliation":[{"name":"Institut des Sciences et Ing\u00e9nierie Chimiques Ecole Polytechnique 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