{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T02:08:58Z","timestamp":1790215738920,"version":"4.1.0"},"reference-count":30,"publisher":"Wiley","issue":"33","license":[{"start":{"date-parts":[[2019,5,20]],"date-time":"2019-05-20T00:00:00Z","timestamp":1558310400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100007215","name":"Verband der Chemischen Industrie","doi-asserted-by":"publisher","award":["Liebig Fellowship"],"award-info":[{"award-number":["Liebig Fellowship"]}],"id":[{"id":"10.13039\/100007215","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2019,6,12]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The synthesis of the <jats:italic>N<\/jats:italic>\u2010aminocarbazole R\u2010NH<jats:sub>2<\/jats:sub> (<jats:bold>2<\/jats:bold>) is reported. Subsequent reaction with bis[bis(trimethylsilyl)amido]tetrylenes E[N(SiMe<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>]<jats:sub>2<\/jats:sub> (E=Ge, Sn, or Pb) allowed the isolation of formal hydrazidotetrylene derivatives, R\u2212N(H)EN(SiMe<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub> (<jats:bold>3<\/jats:bold>) that includes the first example of a hydrazidoplumbylene to date. Thermal decomposition of these compounds resulted in the elimination of \u201cNH\u201d and afforded the tetrylenes R\u2010EN(SiMe<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub> (<jats:bold>4<\/jats:bold>).<\/jats:p>","DOI":"10.1002\/chem.201901573","type":"journal-article","created":{"date-parts":[[2019,4,15]],"date-time":"2019-04-15T12:16:27Z","timestamp":1555330587000},"page":"7843-7846","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Synthesis and Thermal Decomposition of Heavy Tetrylenes Bearing <i>N<\/i>\u2010Aminocarbazolyl Substituents"],"prefix":"10.1002","volume":"25","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7831-1410","authenticated-orcid":false,"given":"Alexander","family":"Hinz","sequence":"first","affiliation":[{"name":"Institute of Inorganic Chemistry (AOC) Karlsruhe Institute of Technology (KIT)  Engesserstr. 15, Geb\u00e4ude 30.45 76131 Karlsruhe 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