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Therefore, it is essential to know their reactivity with beryllium compounds in order to assess its effects in the body. The reactivity of simple aldehydes towards beryllium halides (F, Cl, Br, I) was studied through solution and solid\u2010state techniques and revealed distinctively different reactivities of the beryllium halides, with BeF<jats:sub>2<\/jats:sub> being the least and BeI<jats:sub>2<\/jats:sub> the most reactive. Rearrangement and aldol condensation reactions were observed and monitored by in situ NMR spectroscopy. Crystal structures of various compounds obtained by Be<jats:sup>2+<\/jats:sup>\u2010catalyzed cyclization, rearrangement, and aldol addition reactions or ligation of beryllium halides have been determined, including unprecedented one\u2010dimensional BeCl<jats:sub>2<\/jats:sub> chains and the first structurally characterized example of an 1\u2010iodo\u2010alkoxide. Long\u2010term studies showed that only aldehydes without a \u03b2\u2010H can form stable beryllium complexes, whereas other aldehydes are oligo\u2010 and polymerized or decomposed by beryllium halides.<\/jats:p>","DOI":"10.1002\/chem.201902414","type":"journal-article","created":{"date-parts":[[2019,7,2]],"date-time":"2019-07-02T06:24:24Z","timestamp":1562048664000},"page":"11147-11156","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":28,"title":["Beryllium\u2010Induced Conversion of Aldehydes"],"prefix":"10.1002","volume":"25","author":[{"given":"Matthias","family":"M\u00fcller","sequence":"first","affiliation":[{"name":"Anorganische Chemie Nachwuchsgruppe Berylliumchemie Fachbereich Chemie Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Stra\u00dfe 4 35032 Marburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3242-6797","authenticated-orcid":false,"given":"Magnus R.","family":"Buchner","sequence":"additional","affiliation":[{"name":"Anorganische Chemie Nachwuchsgruppe Berylliumchemie Fachbereich Chemie Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Stra\u00dfe 4 35032 Marburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2019,8]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1141199"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules15085258"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201601203"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5b02698"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-2836(03)00761-7"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/ciuz.19930270611"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201601809"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201601809"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.theochem.2010.07.011"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol025719l"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo00152a011"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2015.03.040"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(96)06229-8"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(97)01051-X"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol047640h"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1055\/s-1998-2053"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/ie401562j"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(02)01899-3"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201803667"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201803667"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201800177"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0567740875004724"},{"key":"e_1_2_7_21_1","first-page":"1","volume-title":"Reference Module in Chemistry, Molecular Sciences and Chemical Engineering","author":"Buchner M.","year":"2017"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1515\/znb-1998-1110"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201103012"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja046712x"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201610956"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201610956"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.5560\/ZNB.2011.66b0055"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.201000129"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic970319t"},{"key":"e_1_2_7_29_1","first-page":"1619","volume":"45","author":"Trojanov S. 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