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This is surprising since several unique synthetic possibilities arise directly from the low stability of their central carbon\u2013iodine bond. In this respect, these high\u2010oxidation\u2010state iodine compounds resemble environmentally benign variants of the prominent metal counterparts such as those derived from palladium, nickel and copper. This Concept article summarizes the general reactivity trends in alkyliodine(III) chemistry and discusses selected examples of their strategic use as highly reactive, transient species in organic synthesis and homogeneous catalysis.<\/jats:p>","DOI":"10.1002\/chem.201902687","type":"journal-article","created":{"date-parts":[[2019,7,30]],"date-time":"2019-07-30T10:07:45Z","timestamp":1564481265000},"page":"13654-13664","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Alkyliodines in High Oxidation State: Enhanced Synthetic Possibilities and Accelerated Catalyst Turn\u2010Over"],"prefix":"10.1002","volume":"25","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9240-5598","authenticated-orcid":false,"given":"Alexandra E.","family":"Bosnidou","sequence":"first","affiliation":[{"name":"Institute of Chemical Research of Catalonia (ICIQ) The Barcelona Institute of Science and Technology  Av. 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