{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,9]],"date-time":"2026-05-09T07:22:40Z","timestamp":1778311360963,"version":"3.51.4"},"reference-count":36,"publisher":"Wiley","issue":"61","license":[{"start":{"date-parts":[[2019,10,9]],"date-time":"2019-10-09T00:00:00Z","timestamp":1570579200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2019,11,4]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The systematic assembly of supramolecular arrangements is a persistent challenge in modern coordination chemistry, especially where further aspects of complexity are concerned, as in the case of large molecular mixed\u2010metal arrangements. One targeted approach to such heterometallic complexes is to engineer metal\u2010based donor ligands of the correct geometry to build 3D arrangements upon coordination to other metals. This simple idea has, however, only rarely been applied to main group metal\u2010based ligand systems. Here, we show that the new, bench\u2010stable tris(3\u2010pyridyl)stannane ligand PhSn(3\u2010Py)<jats:sub>3<\/jats:sub> (3\u2010Py=3\u2010pyridyl) provides simple access to a range of heterometallic Sn<jats:sup>IV<\/jats:sup>\/transition metal complexes, and that the presence of weakly coordinating counter anions can be used to build discrete molecular arrangements involving anion encapsulation. This work therefore provides a building strategy in this area, which parallels that of supramolecular transition metal chemistry.<\/jats:p>","DOI":"10.1002\/chem.201903498","type":"journal-article","created":{"date-parts":[[2019,8,30]],"date-time":"2019-08-30T05:20:06Z","timestamp":1567142406000},"page":"14003-14009","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["A Tris(3\u2010pyridyl)stannane as a Building Block for Heterobimetallic Coordination Polymers and Supramolecular Cages"],"prefix":"10.1002","volume":"25","author":[{"given":"Eric S.","family":"Yang","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Cambridge  Lensfield Road Cambridge CB2 1EW UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alex J.","family":"Plajer","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Cambridge  Lensfield Road Cambridge CB2 1EW UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"\u00c1lvaro","family":"Garc\u00eda\u2010Romero","sequence":"additional","affiliation":[{"name":"GIR MIOMeT-IU Cinquima-Qu\u00edmica Inorg\u00e1nica Facultad de Ciencias Universidad de Valladolid  Campus Miguel, Delibes 47011 Valladolid Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Andrew D.","family":"Bond","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Cambridge  Lensfield Road Cambridge CB2 1EW UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tanya K.","family":"Ronson","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Cambridge  Lensfield Road Cambridge CB2 1EW UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Celedonio M.","family":"\u00c1lvarez","sequence":"additional","affiliation":[{"name":"GIR MIOMeT-IU Cinquima-Qu\u00edmica Inorg\u00e1nica Facultad de Ciencias Universidad de Valladolid  Campus Miguel, Delibes 47011 Valladolid Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ra\u00fal","family":"Garc\u00eda\u2010Rodr\u00edguez","sequence":"additional","affiliation":[{"name":"GIR MIOMeT-IU Cinquima-Qu\u00edmica Inorg\u00e1nica Facultad de Ciencias Universidad de Valladolid  Campus Miguel, Delibes 47011 Valladolid Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6920-3744","authenticated-orcid":false,"given":"Annie L.","family":"Colebatch","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Cambridge  Lensfield Road Cambridge CB2 1EW UK"},{"name":"Research School of Chemistry Australian National University  Canberra ACT 2601 Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9952-3877","authenticated-orcid":false,"given":"Dominic S.","family":"Wright","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Cambridge  Lensfield Road Cambridge CB2 1EW UK"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2019,10,9]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cs15251g"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4SC03046J"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b13190"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b11152"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201701596"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.7b02516"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1098-1071(1997)8:5<439::AID-HC9>3.0.CO;2-3"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.7b00556"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b07625"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms13169"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201611875"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201611875"},{"key":"e_1_2_7_12_1","unstructured":"\u00a0"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC09671A"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201803342"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5DT04155D"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8DT01332B"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/cc9960002619"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201802350"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201802350"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms3670"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201702113"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic502207f"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.7b02074"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2007.02.127"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200454084"},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200454084"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp8111556"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/9783527639502.ch5"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/b926221k"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2053273314026370"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2053229614024218"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.3390\/cryst7110336"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889809045701"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0907444913000061"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0907444910045749"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201903498","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.201903498","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201903498","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T16:13:59Z","timestamp":1760285639000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.201903498"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,10,9]]},"references-count":36,"journal-issue":{"issue":"61","published-print":{"date-parts":[[2019,11,4]]}},"alternative-id":["10.1002\/chem.201903498"],"URL":"https:\/\/doi.org\/10.1002\/chem.201903498","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2019,10,9]]},"assertion":[{"value":"2019-07-31","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2019-10-09","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}