{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,29]],"date-time":"2026-07-29T23:10:13Z","timestamp":1785366613373,"version":"3.55.0"},"reference-count":67,"publisher":"Wiley","issue":"57","license":[{"start":{"date-parts":[[2019,9,13]],"date-time":"2019-09-13T00:00:00Z","timestamp":1568332800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["TA 189\/16-1"],"award-info":[{"award-number":["TA 189\/16-1"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2019,10,11]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Arsenic monophosphide (AsP) species supported by two different N\u2010heterocyclic carbenes were prepared by reaction of (IDipp)PSiMe<jats:sub>3<\/jats:sub> (<jats:bold>1<\/jats:bold>) (IDipp=1,3\u2010bis(2,6\u2010diisopropylphenyl)imidazolin\u20102\u2010ylidene) with (IMes)AsCl<jats:sub>3<\/jats:sub> (<jats:bold>2<\/jats:bold>) (IMes=1,3\u2010bis(2,4,6\u2010trimethylphenyl)imidazolin\u20102\u2010ylidene) to afford the dichloride [(IMes)As(Cl)P(IDipp)]Cl (<jats:bold>3<\/jats:bold>), which upon reduction with KC<jats:sub>8<\/jats:sub> furnished heteroleptic [(IMes)AsP(IDipp)] (<jats:bold>4<\/jats:bold>). The corresponding mono\u2010 and dications [(IMes)AsP(IDipp)][PF<jats:sub>6<\/jats:sub>], [<jats:bold>5<\/jats:bold>]PF<jats:sub><jats:bold>6<\/jats:bold><\/jats:sub>, and [(IMes)AsP(IDipp)][GaCl<jats:sub>4<\/jats:sub>]<jats:sub>2,<\/jats:sub> [<jats:bold>6<\/jats:bold>][GaCl<jats:sub>4<\/jats:sub>]<jats:sub>2<\/jats:sub>, respectively, were prepared by one\u2010electron oxidation of <jats:bold>4<\/jats:bold> with ferrocenium hexafluorophosphate, [Fc]PF<jats:sub>6,<\/jats:sub> or by chloride abstraction from <jats:bold>3<\/jats:bold> with two equivalents of GaCl<jats:sub>3<\/jats:sub>, respectively. Compounds <jats:bold>4<\/jats:bold>\u2013<jats:bold>6<\/jats:bold> represent rare examples of heterodiatiomic interpnictogen compounds, and X\u2010ray crystal structure determinations together with density functional theory (DFT) calculations reveal a consecutive shortening of the As\u2212P bond lengths and increasing bond order, in agreement with the presence of an arsenic\u2013phosphorus single bond in <jats:bold>4<\/jats:bold> and a double bond in <jats:bold>6<\/jats:bold><jats:sup>2+<\/jats:sup>. The EPR signal of the cationic radical [<jats:bold>5<\/jats:bold>]<jats:sup>+.<\/jats:sup> indicates a symmetric spin distribution on the AsP moiety through strong hyperfine coupling with the <jats:sup>75<\/jats:sup>As and <jats:sup>31<\/jats:sup>P nuclei.<\/jats:p>","DOI":"10.1002\/chem.201903795","type":"journal-article","created":{"date-parts":[[2019,8,21]],"date-time":"2019-08-21T05:54:31Z","timestamp":1566366871000},"page":"13119-13123","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":38,"title":["Isolation of Carbene\u2010Stabilized Arsenic Monophosphide [AsP] and its Radical Cation [AsP]<sup>+.<\/sup> and Dication [AsP]<sup>2+<\/sup>"],"prefix":"10.1002","volume":"25","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1803-4818","authenticated-orcid":false,"given":"Adinarayana","family":"Doddi","sequence":"first","affiliation":[{"name":"Department of Chemical Sciences Indian Institute of Science Education and Research Berhampur, Transit Campus, Govt. 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Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5364-0357","authenticated-orcid":false,"given":"Matthias","family":"Tamm","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische und Analytische Chemie Technische Universit\u00e4t Braunschweig  Hagenring 30 38106 Braunschweig 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