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Until recently such simulations based on electronic structure theory have been performed only by density functional theory and semiempirical methods. Many\u2010body electronic structure methods, almost routinely used for molecules, have been practically unavailable for sampling PES in the condensed\u2010phase. This has changed during the last few years, as efficient algorithms and software implementations for the evaluation of electronic energies and forces on atoms have been developed, allowing for geometry optimization, molecular dynamics and Monte\u2010Carlo simulations, which was previously unthinkable. Herein, we introduce the theory and software developments and overview the applications in the field, the most encouraging results being obtained for aqueous chemistry. Requiring state\u2010of\u2010the\u2010art computer resources PES sampling with many\u2010body electronic structure methods in the condensed phase provides high\u2010quality benchmarks and will gradually become more available due to fast progress in reduced scaling algorithms and computational technologies.<\/jats:p>","DOI":"10.1002\/chem.201904012","type":"journal-article","created":{"date-parts":[[2019,10,23]],"date-time":"2019-10-23T15:11:12Z","timestamp":1571843472000},"page":"362-368","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Sampling Potential Energy Surfaces in the Condensed Phase with Many\u2010Body Electronic Structure Methods"],"prefix":"10.1002","volume":"26","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5136-6035","authenticated-orcid":false,"given":"Vladimir V.","family":"Rybkin","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Zurich  Winterthurerstrasse 190 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