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The synthesis presented here allows the preparation of small nanoparticles (less than 20\u2005nm in average diameter), well\u2010defined in size and shape, yet highly crystalline and with the highest surface area reported so far (up to 80\u2005m<jats:sup>2<\/jats:sup>\u2009g<jats:sup>\u22121<\/jats:sup>). X\u2010ray diffraction studies show that the final material is not a mixture of single oxides but a distinctive compound. The photocatalytic properties of the oxynitrides have been tested towards the decomposition of an organic dye (as a model reaction for the decomposition of air pollutants), showing better photocatalytic performances than the corresponding pure phases (reaction constant 0.22\u2005h<jats:sup>\u22121<\/jats:sup>), whereas almost no reaction was observed in absence of catalyst or in the dark. The photocatalysts have been also tested for H<jats:sub>2<\/jats:sub> evolution (semi\u2010reaction of the water splitting process) with results comparable to the best literature values but leaving room for further improvement.<\/jats:p>","DOI":"10.1002\/chem.201904033","type":"journal-article","created":{"date-parts":[[2019,10,25]],"date-time":"2019-10-25T12:18:27Z","timestamp":1572005907000},"page":"16676-16682","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Multimetallic Oxynitrides Nanoparticles for a New Generation of Photocatalysts"],"prefix":"10.1002","volume":"25","author":[{"given":"Tingke","family":"Rao","sequence":"first","affiliation":[{"name":"School of Biological and Chemical Science Chemistry Department Queen Mary University of London  Mile End Road London E1 4NS UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maria Luisa","family":"Saladino","sequence":"additional","affiliation":[{"name":"Dipartimento Scienze e Tecnologie Biologiche Chimiche e Farmaceutiche, STEBICEF and INSTM UdR, Palermo Universit\u00e0 di Palermo  Viale delle Scienze pad. 17 Palermo 90128 Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuanxing","family":"Fang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Photocatalysis on Energy and Environment College of Chemistry Fuzhou University  Fuzhou 350002 P. 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