{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,8]],"date-time":"2026-01-08T22:50:47Z","timestamp":1767912647578,"version":"3.49.0"},"reference-count":59,"publisher":"Wiley","issue":"12","license":[{"start":{"date-parts":[[2020,2,21]],"date-time":"2020-02-21T00:00:00Z","timestamp":1582243200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2020,2,26]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A set of titanium oxide clusters (TOCs) comprised of 4 to 16 Ti atoms are synthesized with substituted salicylates (SSAs). The interfacial coordination environment of these SSA\/Ti oxide hybrids are surveyed and found to be limited to four binding modes, with the bridging chelate mode being the most common one. The SSA\u2010functionalized TOCs show strong visible light absorption properties. The contribution of the SSAs in the frontier orbitals of the TOCs are analyzed by using TD\u2010DFT calculations based on the molecular geometries determined by X\u2010ray diffraction. For TOCs of relatively high O\/Ti ratio, the SSAs narrow the band gap of the TOCs by contributing solely to the HOMOs. Both binding modes and locations of the SSAs are important for the roles of SSAs in changing the HOMOs and thereby the absorption onsets.<\/jats:p>","DOI":"10.1002\/chem.201904302","type":"journal-article","created":{"date-parts":[[2019,12,9]],"date-time":"2019-12-09T08:49:58Z","timestamp":1575881398000},"page":"2666-2674","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":30,"title":["Binding Modes of Salicylic Acids to Titanium Oxide Molecular Surfaces"],"prefix":"10.1002","volume":"26","author":[{"given":"Caiyun","family":"Liu","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering Shandong University  Shanda South Road 27 250100 Jinan China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Junyi","family":"Hu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Shandong University  Shanda South Road 27 250100 Jinan China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Weiming","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Shandong University  Shanda South Road 27 250100 Jinan China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Feng","family":"Zhu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Shandong University  Shanda South Road 27 250100 Jinan China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Guo","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Chemistry Capital Normal University  Beijing 100048 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chen\u2010Ho","family":"Tung","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Shandong University  Shanda South Road 27 250100 Jinan China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8103-3087","authenticated-orcid":false,"given":"Yifeng","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Shandong University  Shanda South Road 27 250100 Jinan China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2020,2,21]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00660"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00035a013"},{"key":"e_1_2_7_4_1","unstructured":"\u00a0"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/am507334m"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr500029g"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr300409r"},{"key":"e_1_2_7_8_1","unstructured":"\u00a0"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201902601"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.7b00496"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1188328"},{"key":"e_1_2_7_12_1","unstructured":"\u00a0"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr400724e"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja301238t"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja303692r"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja909600w"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00001D"},{"key":"e_1_2_7_18_1","unstructured":"\u00a0"},{"key":"e_1_2_7_19_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00511C"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC04421E"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0cs00137f"},{"key":"e_1_2_7_22_1","unstructured":"\u00a0"},{"key":"e_1_2_7_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b00982"},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b00129"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b06290"},{"key":"e_1_2_7_26_1","unstructured":"\u00a0"},{"key":"e_1_2_7_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b01071"},{"key":"e_1_2_7_28_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201307721"},{"key":"e_1_2_7_28_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201307721"},{"key":"e_1_2_7_29_1","unstructured":"\u00a0"},{"key":"e_1_2_7_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/am500391w"},{"key":"e_1_2_7_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/am403987b"},{"key":"e_1_2_7_32_1","unstructured":"\u00a0"},{"key":"e_1_2_7_33_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2015.01.041"},{"key":"e_1_2_7_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp9013338"},{"key":"e_1_2_7_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp021235v"},{"key":"e_1_2_7_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/es010613r"},{"key":"e_1_2_7_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/es001109"},{"key":"e_1_2_7_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/la970665n"},{"key":"e_1_2_7_39_2","doi-asserted-by":"publisher","DOI":"10.1021\/la00038a030"},{"key":"e_1_2_7_40_1","unstructured":"\u00a0"},{"key":"e_1_2_7_41_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.poly.2018.10.011"},{"key":"e_1_2_7_42_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8CE00150B"},{"key":"e_1_2_7_43_1","unstructured":"\u00a0"},{"key":"e_1_2_7_44_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2016.01.017"},{"key":"e_1_2_7_45_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja108205q"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201709539"},{"key":"e_1_2_7_46_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201709539"},{"key":"e_1_2_7_47_1","unstructured":"BVS calculations were performed using by the Bond Valence Calculator C. Hormillosa S. Healy (Version 2.0 February 1993)."},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja016930f"},{"key":"e_1_2_7_49_1","unstructured":"\u00a0"},{"key":"e_1_2_7_50_2","doi-asserted-by":"publisher","DOI":"10.1039\/a906198c"},{"key":"e_1_2_7_51_2","doi-asserted-by":"publisher","DOI":"10.1039\/dt9960000691"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp9901904"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp047097m"},{"key":"e_1_2_7_54_1","first-page":"1301249","volume":"4","author":"Tachan Z.","year":"2014","journal-title":"Adv. Mater."},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja106436y"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr900356p"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.8b00904"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.201904302","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201904302","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.201904302","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201904302","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T18:18:51Z","timestamp":1760293131000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.201904302"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,2,21]]},"references-count":59,"journal-issue":{"issue":"12","published-print":{"date-parts":[[2020,2,26]]}},"alternative-id":["10.1002\/chem.201904302"],"URL":"https:\/\/doi.org\/10.1002\/chem.201904302","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020,2,21]]},"assertion":[{"value":"2019-09-18","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2020-02-21","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}