{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T02:57:31Z","timestamp":1789095451230,"version":"build-2803163510"},"reference-count":48,"publisher":"Wiley","issue":"72","license":[{"start":{"date-parts":[[2019,11,26]],"date-time":"2019-11-26T00:00:00Z","timestamp":1574726400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2019,12,20]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Precious\u2010metal catalysts (e.g., Au, Rh, Ag, Ru, Pt, and Pd) supported on transition\u2010metal oxides (e.g., Al<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>, Fe<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>, CeO<jats:sub>2<\/jats:sub>, ZrO<jats:sub>2<\/jats:sub>, Co<jats:sub>3<\/jats:sub>O<jats:sub>4<\/jats:sub>, MnO<jats:sub>2<\/jats:sub>, TiO<jats:sub>2<\/jats:sub>, and NiO) can effectively oxidize volatile organic compounds. In this study, porous platinum\u2010supported zirconia materials have been prepared by a \u201csurface\u2010casting\u201d method. The synthesized catalysts present an ordered nanotube structure and exhibited excellent performance toward the catalytic oxidation of formaldehyde. A facile method, utilizing a boiling water bath, was used to fabricate graphene aerogel (GA), and the macroscopic 3D Pt\/ZrO<jats:sub>2<\/jats:sub>\u2010GA was modified by introducing an adjustable MOF coating by a surface step\u2010by\u2010step method. The unblocked mesoporous structure of the graphene aerogel facilitates the ingress and egress of reactants and product molecules. The selected 7\u2005wt.% Pt\/ZrO<jats:sub>2<\/jats:sub>\u2010GA\u2010MOF\u20105 composite demonstrated excellent performance for HCHO adsorption. Additionally, this catalyst achieved around 90\u2009% conversion when subjected to a reaction temperature of 70\u2009\u00b0C (<jats:italic>T<\/jats:italic><jats:sub>90\u2009%<\/jats:sub>=70\u2009\u00b0C). The Pt\/ZrO<jats:sub>2<\/jats:sub>\u2010GA\u2010MOF\u20105 composite induces a catalytic cycle, increasing the conversion by simultaneously adsorbing and oxidizing HCHO. This work provides a simple approach to increasing reactant concentration on the catalyst to increase the rate of reaction.<\/jats:p>","DOI":"10.1002\/chem.201904426","type":"journal-article","created":{"date-parts":[[2019,10,26]],"date-time":"2019-10-26T00:49:41Z","timestamp":1572050981000},"page":"16718-16724","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":23,"title":["Platinum\u2010Supported Zirconia Nanotube Arrays Supported on Graphene Aerogels Modified with Metal\u2013Organic Frameworks: Adsorption and Oxidation of Formaldehyde at Room Temperature"],"prefix":"10.1002","volume":"25","author":[{"given":"Haocun","family":"Tan","sequence":"first","affiliation":[{"name":"College of Chemistry Chemical Engineering and Materials Science, Collaborative Innovation Center of Suzhou Nano Science and Technology Soochow University  Suzhou 215123 P.R. 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