{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,14]],"date-time":"2025-10-14T01:20:05Z","timestamp":1760404805238,"version":"build-2065373602"},"reference-count":45,"publisher":"Wiley","issue":"5","license":[{"start":{"date-parts":[[2019,12,27]],"date-time":"2019-12-27T00:00:00Z","timestamp":1577404800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100004350","name":"Studienstiftung des Deutschen Volkes","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004350","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2020,1,22]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Octaphosphane {<jats:italic>cyclo<\/jats:italic>\u2010(P<jats:sub>4<\/jats:sub><jats:italic>t<\/jats:italic>Bu<jats:sub>3<\/jats:sub>)}<jats:sub>2<\/jats:sub> (<jats:bold>1<\/jats:bold>) undergoes an unexpected isomerization reaction to the constitutional isomer 2,2\u2032,2\u2032\u2032,2\u2032\u2032\u2032,3,3\u2032\u2010hexa\u2010<jats:italic>tert<\/jats:italic>\u2010butyl\u2010bicyclo[3.3.0]octaphosphane (<jats:bold>2<\/jats:bold>) in the presence of Lewis acidic metal salts. The mechanism of this reaction is discussed and elucidated with DFT calculations. The results underline the fascinating similarity between phosphorus\u2010rich and isolobal carbon compounds. The new bicyclic octaphosphane <jats:bold>2<\/jats:bold> shows a dynamic behavior in solution and reacts with [AuCl(tht)] (tht=tetrahydrothiophene) to give a mono\u2010 ([AuCl(<jats:bold>2<\/jats:bold>\u2010\u03ba<jats:italic>P<\/jats:italic><jats:sup>3<\/jats:sup>)], <jats:bold>3<\/jats:bold>) and a dinuclear complex ([(AuCl)<jats:sub>2<\/jats:sub>(<jats:bold>2<\/jats:bold>\u2010\u03ba<jats:italic>P<\/jats:italic><jats:sup>3<\/jats:sup>,\u03ba<jats:italic>P<\/jats:italic><jats:sup>3\u2032<\/jats:sup>)], <jats:bold>4<\/jats:bold>). With <jats:italic>cis<\/jats:italic>\u2010[PdCl<jats:sub>2<\/jats:sub>(cod)] (cod=1,5\u2010cyclooctadiene), the chelate complex ([PdCl<jats:sub>2<\/jats:sub>(<jats:bold>2<\/jats:bold>\u2010\u03ba<jats:sup>2<\/jats:sup><jats:italic>P<\/jats:italic><jats:sup>2<\/jats:sup>,<jats:italic>P<\/jats:italic><jats:sup>2\u2032<\/jats:sup>)], <jats:bold>5<\/jats:bold>) with a different coordination mode of the ligand was obtained.<\/jats:p>","DOI":"10.1002\/chem.201904531","type":"journal-article","created":{"date-parts":[[2019,11,22]],"date-time":"2019-11-22T22:00:02Z","timestamp":1574460002000},"page":"1008-1012","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Unexpected Isomerization of Hexa\u2010<i>tert<\/i>\u2010butyl\u2010octaphosphane"],"prefix":"10.1002","volume":"26","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9162-6487","authenticated-orcid":false,"given":"Toni","family":"Grell","sequence":"first","affiliation":[{"name":"Faculty of Chemistry and Mineralogy Institute of Inorganic Chemistry Leipzig University  Johannisallee 29 04103 Leipzig Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4267-0603","authenticated-orcid":false,"given":"Evamarie","family":"Hey\u2010Hawkins","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry and Mineralogy Institute of Inorganic Chemistry Leipzig University  Johannisallee 29 04103 Leipzig Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2019,12,27]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.187701001222"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/nadc.20174062644"},{"key":"e_1_2_2_4_1","unstructured":"\u00a0"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00020a010"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00029a005"},{"key":"e_1_2_2_7_1","unstructured":"\u00a0"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr900349u"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100010e"},{"key":"e_1_2_2_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/cplu.201200013"},{"key":"e_1_2_2_11_1","unstructured":"\u00a0"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.201300522"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1515\/pac-2018-0905"},{"key":"e_1_2_2_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00405a054"},{"key":"e_1_2_2_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198802801"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19881000221"},{"volume-title":"Phosphorus. 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