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The mineralization proceeds by a low\u2010temperature dissolution\u2013reprecipitation process from the liquid phase by the formation of basic cobalt zinc salts as intermediates. The crystal shape as well as twin formation of the resulting oxide phase can be influenced by careful choice of the solvent mixture and the amount of doping. An understanding of the course of the reaction was achieved by comprehensive employment of analytical techniques (i.e., SEM, XRD, IR) including an in\u2010depth HRTEM study of precipitates from various reaction stages. In addition, EPR as well as UV\/Vis spectroscopic measurements provide information about the insertion of the cobalt dopant into the zincite lattice. The Langmuir\u2013Blodgett (LB) technique is shown to be suitable for depositing coatings of the platelets on glass substrates functionalized with polyelectrolyte multilayers and hence is applied for the formation of monolayers containing domains with ordered tessellation. No major differences are found between deposits on substrates with anionic or cationic surface modification. The adherence to the substrates is sufficient to determine the absolute orientation of the deposited polar single crystals by piezoresponse force microscopy (PFM) and Kelvin probe force microscopy (KPFM) studies.<\/jats:p>","DOI":"10.1002\/chem.201904638","type":"journal-article","created":{"date-parts":[[2020,1,9]],"date-time":"2020-01-09T04:52:21Z","timestamp":1578545541000},"page":"9319-9329","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Synthesis and Assembly of Zinc Oxide Microcrystals by a Low\u2010Temperature Dissolution\u2013Reprecipitation Process: Lessons Learned About Twin Formation in Heterogeneous Reactions"],"prefix":"10.1002","volume":"26","author":[{"given":"Rudolf C.","family":"Hoffmann","sequence":"first","affiliation":[{"name":"Eduard-Zintl-Institut f\u00fcr Anorganische und Physikalische Chemie Technische Universit\u00e4t Darmstadt  Alarich-Weiss-Strasse 12 64287 Darmstadt 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