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However, their synthesis is quite challenging, particularly due to the limited thermal stability of starting materials like P<jats:sub>3<\/jats:sub>N<jats:sub>5<\/jats:sub>. Typically, it requires even high\u2010pressure techniques (e.g. multianvil) in most cases. Herein, we establish the ammonothermal method as a versatile synthetic tool to access nitridophosphates with different degrees of condensation. \u03b1\u2010Li<jats:sub>10<\/jats:sub>P<jats:sub>4<\/jats:sub>N<jats:sub>10<\/jats:sub>, \u03b2\u2010Li<jats:sub>10<\/jats:sub>P<jats:sub>4<\/jats:sub>N<jats:sub>10<\/jats:sub>, Li<jats:sub>18<\/jats:sub>P<jats:sub>6<\/jats:sub>N<jats:sub>16<\/jats:sub>, Ca<jats:sub>2<\/jats:sub>PN<jats:sub>3<\/jats:sub>, SrP<jats:sub>8<\/jats:sub>N<jats:sub>14<\/jats:sub>, and LiPN<jats:sub>2<\/jats:sub> were synthesized in supercritical NH<jats:sub>3<\/jats:sub> at temperatures and pressures up to 1070\u2005K and 200\u2005MPa employing ammonobasic conditions. The products were analyzed by powder X\u2010ray diffraction, energy dispersive X\u2010ray spectroscopy, and FTIR spectroscopy. Moreover, we established red phosphorus as a starting material for nitridophosphate synthesis instead of commonly used and not readily available precursors, such as P<jats:sub>3<\/jats:sub>N<jats:sub>5<\/jats:sub>. This opens a promising preparative access to the emerging compound class of nitridophosphates.<\/jats:p>","DOI":"10.1002\/chem.201905227","type":"journal-article","created":{"date-parts":[[2020,1,7]],"date-time":"2020-01-07T06:55:02Z","timestamp":1578380102000},"page":"2067-2072","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Crystalline Nitridophosphates by Ammonothermal Synthesis"],"prefix":"10.1002","volume":"26","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2390-1816","authenticated-orcid":false,"given":"Mathias","family":"Mallmann","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Munich (LMU)  Butenandtstra\u00dfe 5\u201313 (D) 81377 Munich Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sebastian","family":"Wendl","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Munich (LMU)  Butenandtstra\u00dfe 5\u201313 (D) 81377 Munich Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4571-8035","authenticated-orcid":false,"given":"Wolfgang","family":"Schnick","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Munich (LMU)  Butenandtstra\u00dfe 5\u201313 (D) 81377 Munich Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2020,1,30]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19693700508"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.196602471"},{"key":"e_1_2_7_2_2","first-page":"208","volume":"78","year":"1966","journal-title":"Angew. 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