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The [Au(C^N)Cl<jats:sub>2<\/jats:sub>] complex\u2005<jats:bold>1<\/jats:bold> featuring the bidentate 2\u2010benzoylpyridine (C<jats:sup>CO<\/jats:sup>N) scaffold was found to react with PTA (1,3,5\u2010triaza\u20107\u2010phosphaadamantane) under mild conditions, including in water, to afford the corresponding phosphonium\u2005<jats:bold>5<\/jats:bold> through C\u2212P reductive elimination. A mechanism is proposed for the title reaction based on in situ <jats:sup>31<\/jats:sup>P{<jats:sup>1<\/jats:sup>H} NMR and HR\u2010ESI\u2010MS analyses combined with DFT calculations. The C\u2212P coupling has been generalized to other C^N cyclometalated Au<jats:sup>III<\/jats:sup> complexes and other tertiary phosphines. Overall, this work provides new insights into the reactivity of cyclometalated Au<jats:sup>III<\/jats:sup> compounds and establishes initial structure\u2013activity relationships to develop Au<jats:sup>III<\/jats:sup>\u2010mediated C\u2212P cross\u2010coupling reactions.<\/jats:p>","DOI":"10.1002\/chem.201905392","type":"journal-article","created":{"date-parts":[[2020,1,29]],"date-time":"2020-01-29T03:23:17Z","timestamp":1580268197000},"page":"4226-4231","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":24,"title":["Carbon\u2013Phosphorus Coupling from C^N Cyclometalated Au<sup>III<\/sup> Complexes"],"prefix":"10.1002","volume":"26","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2699-4384","authenticated-orcid":false,"given":"Riccardo","family":"Bonsignore","sequence":"first","affiliation":[{"name":"School of Chemistry Cardiff University  Main Building, Park Place CF10 3AT Cardiff 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