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Herein, cyanido\u2010bridged coordination clusters {[Fe<jats:sup>II<\/jats:sup>(2\u2010pyrpy)<jats:sub>2<\/jats:sub>]<jats:sub>4<\/jats:sub>[M<jats:sup>IV<\/jats:sup>(CN)<jats:sub>8<\/jats:sub>]<jats:sub>2<\/jats:sub>}<jats:bold>\u22c5<\/jats:bold>4\u2009MeOH<jats:bold>\u22c5<\/jats:bold>6\u2009H<jats:sub>2<\/jats:sub>O (M=Mo (<jats:bold>1\u2009solv<\/jats:bold>), M=W (<jats:bold>2\u2009solv<\/jats:bold>) and 2\u2010pyrpy=2\u2010(1\u2010pyrazolyl)pyridine are presented, which show persistent solvent driven single\u2010crystal\u2010to\u2010single\u2010crystal transformations upon sorption\/desorption of water and methanol molecules. Three full desolvation\u2013resolvation cycles with the concomitant change of the host molecules do not damage the single crystals. 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