{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:35:26Z","timestamp":1786977326748,"version":"build-2736575974"},"reference-count":155,"publisher":"Wiley","issue":"52","license":[{"start":{"date-parts":[[2020,7,8]],"date-time":"2020-07-08T00:00:00Z","timestamp":1594166400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21672067"],"award-info":[{"award-number":["21672067"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21702063"],"award-info":[{"award-number":["21702063"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2020,9,16]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    During the past few decades, there has been considerable growth in the development of denitrogenative reactions of triazole skeletons to construct valuable cyclic compounds, particularly heterocycles. Despite the inherent difficulty of the ring\u2010opening of triazole derivatives, many novel and efficient approaches have arisen in this area mainly with the use of transition metal (such as rhodium, palladium, silver, copper) catalysis, photolysis, or free radical mediated reactions. Generally, these procedures begin with the ring\u2010opening of 1,2,3\u2010triazoles or benzotriazoles followed by N\n                    <jats:sub>2<\/jats:sub>\n                    extrusion and subsequent diverse transformations, which enable the rapid synthesis of various heterocycles in a single step. To avoid overlap with other related reviews, this minireview covers the recent advances in the denitrogenative cyclization of 1,2,3\u2010triazoles since 2016 and the denitrogenative cyclization of benzotriazoles since 2012.\n                  <\/jats:p>","DOI":"10.1002\/chem.202000674","type":"journal-article","created":{"date-parts":[[2020,5,19]],"date-time":"2020-05-19T17:00:09Z","timestamp":1589907609000},"page":"11931-11945","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":92,"title":["Synthesis of Heterocycles through Denitrogenative Cyclization of Triazoles and Benzotriazoles"],"prefix":"10.1002","volume":"26","author":[{"given":"Wenbo","family":"Li","sequence":"first","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes School of Chemistry and Molecular Engineering East China Normal University  3663 N. Zhongshan Road Shanghai 20062 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4636-2846","authenticated-orcid":false,"given":"Junliang","family":"Zhang","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes School of Chemistry and Molecular Engineering East China Normal University  3663 N. Zhongshan Road Shanghai 20062 P. R. China"},{"name":"Department of Chemistry Fudan University  2005 Songhu Road Shanghai 20048 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2020,7,8]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr020095i"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/b606984n"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1cs15082k"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2cs15350e"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr300100s"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr300333u"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/jm501100b"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201500967"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-0036-1588423"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200700804"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200700804"},{"key":"e_1_2_7_12_1","unstructured":"\u00a0"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200604241"},{"key":"e_1_2_7_13_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200604241"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol102087r"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2011.06.017"},{"key":"e_1_2_7_16_1","unstructured":"\u00a0"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/jlac.19093640204"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/jlac.19274590104"},{"key":"e_1_2_7_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00994a034"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0065-2725(08)60459-6"},{"key":"e_1_2_7_21_1","unstructured":"\u00a0"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo00106a041"},{"key":"e_1_2_7_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo00128a040"},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr941170v"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr900204u"},{"key":"e_1_2_7_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr200031r"},{"key":"e_1_2_7_27_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7SC00367F"},{"key":"e_1_2_7_28_1","unstructured":"\u00a0"},{"key":"e_1_2_7_29_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201104807"},{"key":"e_1_2_7_29_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201104807"},{"key":"e_1_2_7_30_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201209338"},{"key":"e_1_2_7_30_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201209338"},{"key":"e_1_2_7_31_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00072B"},{"key":"e_1_2_7_32_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-0034-1379303"},{"key":"e_1_2_7_33_2","doi-asserted-by":"publisher","DOI":"10.1071\/CH15363"},{"key":"e_1_2_7_34_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-0034-1380444"},{"key":"e_1_2_7_35_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201601703"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja805079v"},{"key":"e_1_2_7_37_1","unstructured":"\u00a0"},{"key":"e_1_2_7_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja908075u"},{"key":"e_1_2_7_39_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja910187s"},{"key":"e_1_2_7_40_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol201705k"},{"key":"e_1_2_7_41_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol201949h"},{"key":"e_1_2_7_42_1","unstructured":"\u00a0"},{"key":"e_1_2_7_43_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja202969z"},{"key":"e_1_2_7_44_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja2104203"},{"key":"e_1_2_7_45_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol500874p"},{"key":"e_1_2_7_46_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201209603"},{"key":"e_1_2_7_46_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201209603"},{"key":"e_1_2_7_47_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol502208w"},{"key":"e_1_2_7_48_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja408185c"},{"key":"e_1_2_7_49_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC04786A"},{"key":"e_1_2_7_50_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC01271F"},{"key":"e_1_2_7_51_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b01298"},{"key":"e_1_2_7_52_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201709384"},{"key":"e_1_2_7_52_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201709384"},{"key":"e_1_2_7_53_1","unstructured":"\u00a0"},{"key":"e_1_2_7_54_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja308285r"},{"key":"e_1_2_7_55_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201207820"},{"key":"e_1_2_7_55_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201207820"},{"key":"e_1_2_7_56_2","doi-asserted-by":"publisher","DOI":"10.1039\/C2CC34609E"},{"key":"e_1_2_7_57_1","unstructured":"\u00a0"},{"key":"e_1_2_7_58_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201504013"},{"key":"e_1_2_7_58_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201504013"},{"key":"e_1_2_7_59_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b02428"},{"key":"e_1_2_7_60_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b03143"},{"key":"e_1_2_7_61_1","unstructured":"\u00a0"},{"key":"e_1_2_7_62_2","doi-asserted-by":"publisher","DOI":"10.1039\/b819162j"},{"key":"e_1_2_7_63_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol2014347"},{"key":"e_1_2_7_64_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol4027655"},{"key":"e_1_2_7_65_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja405043g"},{"key":"e_1_2_7_66_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja407166r"},{"key":"e_1_2_7_67_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201304310"},{"key":"e_1_2_7_67_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201304310"},{"key":"e_1_2_7_68_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201206388"},{"key":"e_1_2_7_68_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201206388"},{"key":"e_1_2_7_69_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja400350c"},{"key":"e_1_2_7_70_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja401380d"},{"key":"e_1_2_7_71_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja4025337"},{"key":"e_1_2_7_72_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja401386z"},{"key":"e_1_2_7_73_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja412663a"},{"key":"e_1_2_7_74_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.7b00180"},{"key":"e_1_2_7_75_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5QO00216H"},{"key":"e_1_2_7_76_1","unstructured":"\u00a0"},{"key":"e_1_2_7_77_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6RA02923J"},{"key":"e_1_2_7_78_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2016.04.017"},{"key":"e_1_2_7_79_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.6b00611"},{"key":"e_1_2_7_80_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol502617m"},{"key":"e_1_2_7_81_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b02703"},{"key":"e_1_2_7_82_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b01968"},{"key":"e_1_2_7_83_1","doi-asserted-by":"publisher","DOI":"10.1002\/ajoc.201600466"},{"key":"e_1_2_7_84_1","unstructured":"\u00a0"},{"key":"e_1_2_7_85_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201504914"},{"key":"e_1_2_7_86_2","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201501178"},{"key":"e_1_2_7_87_1","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201900290"},{"key":"e_1_2_7_88_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC02521A"},{"key":"e_1_2_7_89_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7QO00101K"},{"key":"e_1_2_7_90_1","unstructured":"\u00a0"},{"key":"e_1_2_7_91_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9QO00714H"},{"key":"e_1_2_7_92_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.9b01924"},{"key":"e_1_2_7_93_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201700300"},{"key":"e_1_2_7_94_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7QO00703E"},{"key":"e_1_2_7_95_1","unstructured":"\u00a0"},{"key":"e_1_2_7_96_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201306706"},{"key":"e_1_2_7_96_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201306706"},{"key":"e_1_2_7_97_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol500718s"},{"key":"e_1_2_7_98_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201702893"},{"key":"e_1_2_7_99_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b03542"},{"key":"e_1_2_7_100_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6QO00084C"},{"key":"e_1_2_7_101_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.8b03205"},{"key":"e_1_2_7_102_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2015.11.021"},{"key":"e_1_2_7_103_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201800057"},{"key":"e_1_2_7_104_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b03179"},{"key":"e_1_2_7_105_1","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201700882"},{"key":"e_1_2_7_106_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.9b01174"},{"key":"e_1_2_7_107_1","unstructured":"\u00a0"},{"key":"e_1_2_7_108_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.7b02697"},{"key":"e_1_2_7_109_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201705036"},{"key":"e_1_2_7_110_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC02294E"},{"key":"e_1_2_7_111_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC10306B"},{"key":"e_1_2_7_112_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.7b01682"},{"key":"e_1_2_7_113_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8OB00083B"},{"key":"e_1_2_7_114_1","unstructured":"\u00a0"},{"key":"e_1_2_7_115_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo9715229"},{"key":"e_1_2_7_116_2","doi-asserted-by":"publisher","DOI":"10.1002\/jhet.5570360417"},{"key":"e_1_2_7_117_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2009.12.030"},{"key":"e_1_2_7_118_1","unstructured":"\u00a0"},{"key":"e_1_2_7_119_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja994464c"},{"key":"e_1_2_7_120_2","doi-asserted-by":"publisher","DOI":"10.3390\/molecules161210256"},{"key":"e_1_2_7_121_2","doi-asserted-by":"publisher","DOI":"10.3390\/molecules191220695"},{"key":"e_1_2_7_122_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.9b02135"},{"key":"e_1_2_7_123_1","unstructured":"\u00a0"},{"key":"e_1_2_7_124_2","doi-asserted-by":"publisher","DOI":"10.1002\/jhet.5570450314"},{"key":"e_1_2_7_125_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2005.06.028"},{"key":"e_1_2_7_126_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol900113f"},{"key":"e_1_2_7_127_1","unstructured":"\u00a0"},{"key":"e_1_2_7_128_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo3021049"},{"key":"e_1_2_7_129_2","doi-asserted-by":"publisher","DOI":"10.1002\/slct.201801241"},{"key":"e_1_2_7_130_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo4024107"},{"key":"e_1_2_7_131_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5RA01545F"},{"key":"e_1_2_7_132_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.9b00343"},{"key":"e_1_2_7_133_1","doi-asserted-by":"publisher","DOI":"10.1002\/slct.201601830"},{"key":"e_1_2_7_134_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.7b00965"},{"key":"e_1_2_7_135_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.5b00156"},{"key":"e_1_2_7_136_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC07543J"},{"key":"e_1_2_7_137_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b01025"},{"key":"e_1_2_7_138_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201609393"},{"key":"e_1_2_7_138_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201609393"},{"key":"e_1_2_7_139_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8QO00778K"},{"key":"e_1_2_7_140_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.7b03184"},{"key":"e_1_2_7_141_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201904805"},{"key":"e_1_2_7_141_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201904805"},{"key":"e_1_2_7_142_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.5b02699"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.202000674","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202000674","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.202000674","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202000674","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T14:06:40Z","timestamp":1760278000000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202000674"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,7,8]]},"references-count":155,"journal-issue":{"issue":"52","published-print":{"date-parts":[[2020,9,16]]}},"alternative-id":["10.1002\/chem.202000674"],"URL":"https:\/\/doi.org\/10.1002\/chem.202000674","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020,7,8]]},"assertion":[{"value":"2020-02-07","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2020-07-08","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}