{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,12,30]],"date-time":"2025-12-30T08:56:43Z","timestamp":1767085003706,"version":"build-2065373602"},"reference-count":48,"publisher":"Wiley","issue":"34","license":[{"start":{"date-parts":[[2021,4,16]],"date-time":"2021-04-16T00:00:00Z","timestamp":1618531200000},"content-version":"am","delay-in-days":326,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#am"},{"start":{"date-parts":[[2020,5,25]],"date-time":"2020-05-25T00:00:00Z","timestamp":1590364800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100000038","name":"Natural Sciences and Engineering Research Council of Canada","doi-asserted-by":"publisher","award":["NSERC DG: RGPIN-2016-04204, NSERC DG:RGPIN-2018-05531"],"award-info":[{"award-number":["NSERC DG: RGPIN-2016-04204, NSERC DG:RGPIN-2018-05531"]}],"id":[{"id":"10.13039\/501100000038","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["CHE12-13529"],"award-info":[{"award-number":["CHE12-13529"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2020,6,18]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Catenation is common for the light main\u2010group elements whereas it is rare for the heavy elements. Herein, we report the first example of a neutral molecule containing a Bi<jats:sub>4<\/jats:sub> chain. It is prepared in a one\u2010step reaction between bismuth trichloride and bis(diisopropylphosphino)amine in methanol suspension. The same reaction carried out in dichloromethane gives quite different products. All products have been characterized spectroscopically and using single\u2010crystal X\u2010ray analysis.<\/jats:p>","DOI":"10.1002\/chem.202001295","type":"journal-article","created":{"date-parts":[[2020,4,16]],"date-time":"2020-04-16T13:00:48Z","timestamp":1587042048000},"page":"7711-7719","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Heavy Metals Make a Chain: A Catenated Bismuth Compound"],"prefix":"10.1002","volume":"26","author":[{"given":"Robert D.","family":"Riley","sequence":"first","affiliation":[{"name":"Department of Chemistry Saint Mary's University  Halifax Nova Scotia B3H 3C3 Canada"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0939-3309","authenticated-orcid":false,"given":"Diane A.","family":"Dickie","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Biology University of New Mexico  Albuquerque New Mexico 87131 USA"},{"name":"Current address: Department of Chemistry University of Virginia  Charlottesville Virginia 22904 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5861-242X","authenticated-orcid":false,"given":"Michael A.","family":"Land","sequence":"additional","affiliation":[{"name":"Department of Chemistry Saint Mary's University  Halifax Nova Scotia B3H 3C3 Canada"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2063-3812","authenticated-orcid":false,"given":"Richard A.","family":"Kemp","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Biology University of New Mexico  Albuquerque New Mexico 87131 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0574-1524","authenticated-orcid":false,"given":"Charles L. B.","family":"Macdonald","sequence":"additional","affiliation":[{"name":"Carleton University, 203 Steacie Building  1125 Colonel By Drive Ottawa Ontario K1S 5B6 Canada"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8237-5855","authenticated-orcid":false,"given":"Ulrike","family":"Werner\u2010Zwanziger","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Clean Technologies Research Institute, NMR-3 Dalhousie University  Halifax Nova Scotia B3H 4R2 Canada"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5602-8059","authenticated-orcid":false,"given":"Katherine N.","family":"Robertson","sequence":"additional","affiliation":[{"name":"Department of Chemistry Saint Mary's University  Halifax Nova Scotia B3H 3C3 Canada"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0722-4862","authenticated-orcid":false,"given":"Jason A. C.","family":"Clyburne","sequence":"additional","affiliation":[{"name":"Department of Chemistry Saint Mary's University  Halifax Nova Scotia B3H 3C3 Canada"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2020,5,25]]},"reference":[{"volume-title":"Comprehensive Inorganic Chemistry\u2005II: From Elements to Applications","year":"2013","key":"e_1_2_7_1_1"},{"volume-title":"Phosphorus: The Carbon Copy","year":"1998","author":"Dillon K. B.","key":"e_1_2_7_2_1"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201307658"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201307658"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201503074"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201503074"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201210012"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201210012"},{"key":"e_1_2_7_6_1","first-page":"1","volume-title":"The Chemistry of Arsenic, Antimony and Bismuth, in Biological Chemistry of Arsenic, Antimony and Bismuth","author":"Burford N.","year":"2010"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1123945"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr00085a006"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201801882"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaz2258"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja992422i"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2052520616003954"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200800839"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3749(200211)628:11<2537::AID-ZAAC2537>3.0.CO;2-A"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201712884"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201712884"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200390176"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic000925f"},{"key":"e_1_2_7_18_1","unstructured":"\u00a0"},{"key":"e_1_2_7_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.7b01051"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.5b02031"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/om500856p"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic401498r"},{"key":"e_1_2_7_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic201697g"},{"key":"e_1_2_7_24_1","unstructured":"\u00a0"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00153"},{"key":"e_1_2_7_26_2","doi-asserted-by":"publisher","DOI":"10.1016\/0277-5387(95)00103-Y"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201100821"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja981575n"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201803664"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic951262i"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/dt9960001063"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2015.10.010"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201705577"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198402721"},{"key":"e_1_2_7_34_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19840960405"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/om50006a027"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.277.5322.78"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.327"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201903683"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2006.07.007"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr980425s"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201903354"},{"key":"e_1_2_7_41_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201903354"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.9b02314"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.202001295","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202001295","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.202001295","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/am-pdf\/10.1002\/chem.202001295","content-type":"application\/pdf","content-version":"am","intended-application":"syndication"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202001295","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T12:54:43Z","timestamp":1760273683000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202001295"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,5,25]]},"references-count":48,"journal-issue":{"issue":"34","published-print":{"date-parts":[[2020,6,18]]}},"alternative-id":["10.1002\/chem.202001295"],"URL":"https:\/\/doi.org\/10.1002\/chem.202001295","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"type":"print","value":"0947-6539"},{"type":"electronic","value":"1521-3765"}],"subject":[],"published":{"date-parts":[[2020,5,25]]},"assertion":[{"value":"2020-03-15","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2020-05-25","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}