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The synthesized 36\u2010molybdate cluster was characterized by routine techniques and tested as a heterogeneous catalyst for selective oxidation of sulfides with impressive catalytic and selective performances after heat treatment. High efficiency (TON=15333) was achieved in the selective oxidation of sulfides to sulfoxides, caused by the synergic effect between copper and polyoxomolybdates and the generation of the cuprous species during the heat treatment.<\/jats:p>","DOI":"10.1002\/chem.202001468","type":"journal-article","created":{"date-parts":[[2020,6,16]],"date-time":"2020-06-16T10:09:58Z","timestamp":1592302198000},"page":"14896-14902","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":24,"title":["36\u2010Nuclearity Organophosphonate\u2010Functionalized Polyoxomolybdates: Synthesis, Characterization and Selective Catalytic Oxidation of Sulfides"],"prefix":"10.1002","volume":"26","author":[{"given":"Qiaofei","family":"Xu","sequence":"first","affiliation":[{"name":"Henan Key Laboratory of Polyoxometalate Chemistry Institute of Molecular and Crystal Engineering College of Chemistry and Chemical Engineering Henan University  Kaifeng Henan 475004 P. R. 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