{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,30]],"date-time":"2026-03-30T17:42:48Z","timestamp":1774892568512,"version":"3.50.1"},"reference-count":65,"publisher":"Wiley","issue":"45","license":[{"start":{"date-parts":[[2020,7,20]],"date-time":"2020-07-20T00:00:00Z","timestamp":1595203200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100010198","name":"Ministerio de Econom\u00eda, Industria y Competitividad, Gobierno de Espa\u00f1a","doi-asserted-by":"publisher","award":["CTQ2017-82893-C2-1-R"],"award-info":[{"award-number":["CTQ2017-82893-C2-1-R"]}],"id":[{"id":"10.13039\/501100010198","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100005604","name":"Universidad de Huelva","doi-asserted-by":"publisher","award":["PO FEDER 2014-2020"],"award-info":[{"award-number":["PO FEDER 2014-2020"]}],"id":[{"id":"10.13039\/501100005604","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2020,8,12]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A family of phosphine ligands containing a five\u2010membered ring similar to the popular N\u2010heterocyclic carbene ligands and an alkoxy third substituent has been developed. These alkoxydiaminophosphine ligands (ADAP) can be generated in one pot and reacted with a copper(I) source leading to the high yield isolation of complexes [(ADAP)CuX]<jats:sub>2<\/jats:sub> (X=Cl, Br). The dinuclear nature of these compounds has been established by means of X\u2010ray studies and DOSY experiments. A screening of the catalytic properties of these complexes toward carbene\u2010transfer reactions from diazocompounds to C\u2212H bonds (alkane, arene), olefins or N\u2212H bonds, as well as in CuAAC or nitrene transfer reactions have shown a performance at least similar, if not better, than their (NHC)CuCl analogues, opening a new window in copper catalysis with these readily tunable ADAP ligands.<\/jats:p>","DOI":"10.1002\/chem.202001517","type":"journal-article","created":{"date-parts":[[2020,4,24]],"date-time":"2020-04-24T06:55:12Z","timestamp":1587711312000},"page":"10330-10335","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Alkoxydiaminophosphine Ligands as Surrogates of NHCs in Copper Catalysis"],"prefix":"10.1002","volume":"26","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2327-3637","authenticated-orcid":false,"given":"Juan Diego","family":"Pizarro","sequence":"first","affiliation":[{"name":"Laboratorio de Cat\u00e1lisis Homog\u00e9nea Unidad Asociada al CSIC CIQSO-Centro de, Investigaci\u00f3n en Qu\u00edmica Sostenible and Departamento de Qu\u00edmica Universidad de Huelva  21007 Huelva Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Francisco","family":"Molina","sequence":"additional","affiliation":[{"name":"Laboratorio de Cat\u00e1lisis Homog\u00e9nea Unidad Asociada al CSIC CIQSO-Centro de, Investigaci\u00f3n en Qu\u00edmica Sostenible and Departamento de Qu\u00edmica Universidad de Huelva  21007 Huelva Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5078-1800","authenticated-orcid":false,"given":"Manuel R.","family":"Fructos","sequence":"additional","affiliation":[{"name":"Laboratorio de Cat\u00e1lisis Homog\u00e9nea Unidad Asociada al CSIC CIQSO-Centro de, Investigaci\u00f3n en Qu\u00edmica Sostenible and Departamento de Qu\u00edmica Universidad de Huelva  21007 Huelva Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6899-4641","authenticated-orcid":false,"given":"Pedro J.","family":"P\u00e9rez","sequence":"additional","affiliation":[{"name":"Laboratorio de Cat\u00e1lisis Homog\u00e9nea Unidad Asociada al CSIC CIQSO-Centro de, Investigaci\u00f3n en Qu\u00edmica Sostenible and Departamento de Qu\u00edmica Universidad de Huelva  21007 Huelva Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2020,7,20]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00001a054"},{"key":"e_1_2_7_2_1","unstructured":"\u00a0"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00634"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr900074m"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2004.05.013"},{"key":"e_1_2_7_6_1","unstructured":"\u00a0"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature13384"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2014.12.019"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/b711132k"},{"key":"e_1_2_7_10_1","unstructured":"\u00a0"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201709926"},{"key":"e_1_2_7_11_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201709926"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201801300"},{"key":"e_1_2_7_12_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201801300"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201611570"},{"key":"e_1_2_7_13_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201611570"},{"key":"e_1_2_7_14_1","unstructured":"\u00a0"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.7b03829"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b03709"},{"key":"e_1_2_7_17_1","unstructured":"\u00a0"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.200600340"},{"key":"e_1_2_7_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200602222"},{"key":"e_1_2_7_19_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200602222"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja406730t"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2014.06.009"},{"key":"e_1_2_7_22_1","unstructured":"\u00a0"},{"key":"e_1_2_7_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201500834"},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2016.02.007"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199117091"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19911031213"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/b111121n"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/om034016k"},{"key":"e_1_2_7_28_1","unstructured":"\u00a0"},{"key":"e_1_2_7_29_2","unstructured":"https:\/\/www.molnac.unisa.it\/OMtools\/sambvca2.0;"},{"key":"e_1_2_7_30_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200801160"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/b922984a"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja047284y"},{"key":"e_1_2_7_33_1","unstructured":"\u00a0"},{"key":"e_1_2_7_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/om200206m"},{"key":"e_1_2_7_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.6b00604"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/om0507474"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5OB01457C"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201705664"},{"key":"e_1_2_7_38_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201705664"},{"key":"e_1_2_7_39_1","unstructured":"\u00a0"},{"key":"e_1_2_7_40_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2008.10.114"},{"key":"e_1_2_7_41_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja069314y"},{"key":"e_1_2_7_42_1","unstructured":"See for example:"},{"key":"e_1_2_7_43_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9SC03354H"},{"key":"e_1_2_7_44_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201308501"},{"key":"e_1_2_7_44_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201308501"},{"key":"e_1_2_7_45_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3ob41331d"},{"key":"e_1_2_7_46_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201203962"},{"key":"e_1_2_7_46_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201203962"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2dt32439c"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.188501802118"},{"key":"e_1_2_7_49_1","unstructured":"\u00a0"},{"key":"e_1_2_7_50_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200600961"},{"key":"e_1_2_7_51_2","first-page":"39","author":"D\u00edez-Gonz\u00e1lez S.","journal-title":"t"},{"key":"e_1_2_7_52_2","doi-asserted-by":"publisher","DOI":"10.1039\/b806806b"},{"key":"e_1_2_7_53_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200803289"},{"key":"e_1_2_7_53_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200803289"},{"key":"e_1_2_7_54_2","doi-asserted-by":"publisher","DOI":"10.1021\/cs500326e"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9SC01657K"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.8b01638"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.202001517","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202001517","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.202001517","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202001517","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T09:39:13Z","timestamp":1760261953000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202001517"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,7,20]]},"references-count":65,"journal-issue":{"issue":"45","published-print":{"date-parts":[[2020,8,12]]}},"alternative-id":["10.1002\/chem.202001517"],"URL":"https:\/\/doi.org\/10.1002\/chem.202001517","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020,7,20]]},"assertion":[{"value":"2020-03-30","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2020-07-20","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}